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Sb掺杂二氧化锡单片纳米带的气敏特性研究
  • ISSN号:1005-023X
  • 期刊名称:材料导报
  • 时间:2015.7.25
  • 页码:87-90
  • 分类:TB34[一般工业技术—材料科学与工程] O48[理学—固体物理;理学—物理]
  • 作者机构:[1]云南师范大学物理与电子信息学院,昆明650500
  • 相关基金:国家自然科学基金(10764005;11164034);教育部新世纪优秀人才项目(NCET-08-0926);云南省自然科学基金(2010DC053;2013FA035);云南省高端科技人才项目(2012HA007)
  • 相关项目:二氧化锡衍生物纳米带的气敏、光化敏感性质及应用研究
中文摘要:

利用热蒸发法制备了纯净的SnO2纳米带及Sb掺杂SnO2纳米带。通过扫描电子显微镜(SEM)、X射线衍射(XRD)、透射电子显微镜(TEM)和气敏测试仪器对其结构和性能进行了表征和测试。结果表明纳米带表面光滑,厚度约为50nm。纯净SnO2纳米带为理想的单晶结构,掺杂Sb后并没有改变二氧化锡的晶体结构和晶胞参数。使用单根Sb掺杂和纯净的SnO2纳米带制作成传感器并进行气敏性能测试,结果显示:Sb掺杂SnO2纳米带对乙二醇和丙酮的最佳响应温度为180℃,在100×10-6浓度下对乙二醇和丙酮的气敏响应分别为10倍和1.2倍;对乙醇的最佳响应温度为200℃,响应为2.6倍。在最佳响应温度,随乙二醇浓度的增加器件气敏响应增强,其响应时间随乙二醇浓度的增加而缩短,在50×10-6及100×10-6时,其响应时间分别为15s和14s。

英文摘要:

Pure SnOz nanoribbons (SnOz NRs) and Sb-doped SnOz nanoribbons (Sb-SnOz NRs) were synthe- sized successfully by thermal evaporation. The structures and properties of the obtained SnOz NRs were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM). It was found that nanoribbons had a smooth surface with thickness of about 50 nm Pure SnO2 NRs have an ideal single-crystal structure, and doping did not change the crystal structure and pa- rameters. A novel ethanediol sensor based on a single Sb-SnOz nanoribbon or SnOz nanoribbon was fabricated. The sensing properties of SnO2 nanoribbon (SnOz NR) and Strdoped SnOz nanoribbon(Sb-SnO2 NR)sensors were investi- gated. The results revealed that the optimum sensing temperature of the Sb-SnO2 NR was 180 ℃ ,and the correspon- ding S value were 10 and 1.2 to 100× 10-6 ethanediol and acetone gases, respectively. The optimum sensing tempera- ture of the Sb-SnOz NR sensor was 200 ℃, while S value was reduced to 2.6 when exposed to 100× 10-6 ethanol gas. The response of the Sb-SnOz NR sensor increased with the increase of concentration of ethanediol gas and the response time were 15 s and 14 s as its concentrations were 50× 10-6 and 100× 10-6 respectively at the optimum sensing tem- perature.

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期刊信息
  • 《材料导报:纳米与新材料专辑》
  • 主管单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主办单位:重庆西南信息有限公司(原科技部西南信息中心)
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  • 地址:重庆市渝北区洪湖西路18号
  • 邮编:401121
  • 邮箱:matreved@163.com
  • 电话:023-67398525
  • 国际标准刊号:ISSN:1005-023X
  • 国内统一刊号:ISSN:50-1078/TB
  • 邮发代号:
  • 获奖情况:
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  • 被引量:3397