通过XRD、H2-TPR、NH3(NO)-TPD和N2吸附-脱附等分析测试手段,研究了Ni掺杂锰氧化物催化剂选择催化还原NO活性的影响。研究发现Ni0.3Mn0.7Ox催化剂的NH3选择催化还原NO的活性最好,其可能原因是掺杂Ni后Ni0.3Mn0.7Ox催化剂的氧化还原能力得到提高,比表面积和孔容增加及有利于低温NH3和NO的吸附。
Ni doping manganese oxides catalysts were studied for selective catalytic reduction of NO by XRD, H2- TPR, NH3 (NO)-TPD and N2 adsorption-desorption. The study found that the catalyst Ni0.3 Mn0.7Ox showed the best selective catalytic reduction activity, the reasons may be as follows: Ni0.3 Mn0.7Ox catalyst showed improved redox, increased specific surface area and pore volume, at the same time, added NH3 and NO adsorption at low temperature.