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Mo2FeB2基金属陶瓷烧结过程中显微组织和力学性能的变化
  • 期刊名称:郑建智,郑勇*,庞旭明,承新,江赛华,林新刚,Mo2FeB2基金属陶瓷烧结过程中显微组织和力学性能的
  • 时间:0
  • 分类:TG174.22[金属学及工艺—金属表面处理;金属学及工艺—金属学] TG148[金属学及工艺—金属材料;一般工业技术—材料科学与工程;金属学及工艺—金属学]
  • 作者机构:[1]南京航空航天大学材料科学与技术学院,江苏南京210016
  • 相关基金:国家自然科学基金(50674057)、苏州市科技发展计划(SG0836)资助项目.
  • 相关项目:脉冲放电机械合金化制备纳米Ti(C,N)粉体材料基础研究
中文摘要:

采用真空烧结法制备了Mo2FeB2基金属陶瓷。运用XRD、SEM、EDS研究了Mo2FeB2基金属陶瓷的烧结过程中显微组织的变化并测试了不同烧结温度下所得金属陶瓷材料的力学性能。实验结果表明:进入L1液相(奥氏体+Fe2B)烧结阶段后,金属陶瓷由于颗粒重排致密度大幅度提高,但溶解一析出过程进行得较缓慢,晶粒基本没有长大。提高烧结温度至L2液相(奥氏体+L1+Mo2FeB2)生成后,由于溶解-析出过程明显加剧,晶粒长大趋势明显,但致密化程度进一步提高。当烧结温度达到1280℃,保温时间为40min时,烧结体接近完全致密,所得材料组织均匀具有较佳力学性能。

英文摘要:

Mo2FeB2-based cermets were prepared by vacuum sintering. The microstructure evolution during the sintering of Mo2FeB2-based cermets was studied by XRD, SEM and EDS. The mechanical properties of the cermets sintered at different temperatures were also tested. The results show that the considerable densification resulted from the rearrangement of ceramic particles during L1 liquid phase (austenite+Fe2B) sintering. However, the grains hardly grew up because the process of dissolution and precipitation was very slow at this stage. When the sintering temperature was increased to which L2 liquid phase (austenite+L1 + Mo2FeB2) formed, the grains grew up rapidly due to the faster process of solution-precipitation. When being sintered at 1280℃for 40 minutes, the cermets achieved nearly complete densification and had superior mechanical properties and homogeneous microstructure.

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