采用电聚合方法将孔雀石绿非共价修饰到碳纳米管上,制备了新颖的聚孔雀石绿/碳纳米管修饰电极。以多巴胺和抗坏血酸为模型化合物,研究了该修饰电极的电催化作用。结果表明:电聚合法使孔雀石绿牢固地修饰到碳纳米管上,与裸电极相比,可以消除抗坏血酸的干扰,峰电流增加两倍以上,较好地提高了电极的灵敏度和分子识别性能,有利于在大量抗坏血酸存在下实现对多巴胺的选择性测定。在2×10^-3mol/L的抗坏血酸的存在下,多巴胺的差分脉冲伏安法峰电流在1×10^-7~1×10^-5mol/L范围内呈良好的线性关系,检测下限达1×10^-7mol/L。
A novel modified electrode was constructed by electro polymerizing malachite green onto carbon nanotubes on the surface of a glassy carbon electrode. Taking dopamine (DA) and ascorbic acid (AA) as model compounds, the modified electrode showed a favorable ability of discrimination and sensibility. A different pulse voltammetric technique for measurement of dopamine over the range of 1 ×10^-7 -1×10^-3 mol/L has been developed. The detection limit was 1 ×10^-7 mol/L.