采用电聚合方法将茜素红非共价修饰到碳纳米管上,制备了聚茜素红/碳纳米管修饰电极。以多巴胺(DA)和抗坏血酸(AA)为模型化合物,研究该修饰电极的电催化作用。结果表明:电聚合法使茜素红牢固地修饰到碳纳米管上,能显著提高电极的灵敏度和分子识别性能。DA和AA的氧化峰位分离达240 mV。在AA的存在下,DA的差分脉冲伏安法峰电流在1×10^-7~1×10^-5mol/L范围内呈良好的线性关系,检测下限达1×10^-7mol/L。
A novel modified electrode was constructed by electro polymerizing alizarin red onto carbon nanotubes on the surface of a glassy carbon electrode. Taking dopamine (DA) and ascorbic acid (AA) as model compounds, the modified electrode showed a favorable ability of discrimination and sensibility, and the anodic peak potential difference (△Epa) was more than 250 mV. DA and AA can be determined simultaneously. A differential pulse voltammetric technique for measurement of dopamine over the range of 1 × 10^-7 - 1 × 10^-5 mol/L has been developed. The detection limit was 1 × 10^-7 mol/L.