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有机硅改性腰果酚醛聚合物涂料的制备与性能研究
  • ISSN号:1000-5277
  • 期刊名称:《福建师范大学学报:自然科学版》
  • 时间:0
  • 分类:O636[理学—高分子化学;理学—化学]
  • 作者机构:[1]福建师范大学化学与材料学院,福建福州350108, [2]福建省湄洲湾职业技术学院化学工程与技术系,福建莆田351007
  • 相关基金:国家自然科学基余资助项目(50473063)
中文摘要:

用二甲基二氯硅烷(DMS)对腰果酚醛聚合物(CF)进行改性,制备了有机硅改性腰果酚醛聚合物涂料(CF-Si),并用IR、UV、DMTA、TG等对CF-Si进行了结构表征和性能测试。结果表明,CF分子中的酚羟基与DMS的Si原子相结合,降低了CF-Si分子中的酚羟基浓度,不仅使CF-Si的固化成膜时间缩短为25min,而且提高了其涂膜的理化性能。当CF与DMS的物质的量比为12.5:3,反应时间25min时,制得的CF-Si涂膜的硬度2H、附着力2级、光泽度128%、耐冲击性45cm、柔韧性1mm;具有很好的热稳定性,400-500℃时,CF的热失重速率是CF-Si的两倍;紫外光照射1400h后,CF-Si的失光率仅为27%,而CF达到58%;CF-Si的耐碱性较CF优异。

英文摘要:

Cardanol-aldehyde condensation resin (CF) was modified with dimethyldichlorosilane (DMS) to prepare cardanol-aldehyde condensation resin modified with organic silicon (CF-Si). The structure and properties of CF-Si were examined by IR, UV, DMTA, TG and other measures. Results showed that silicon-oxygen bond in CF-Si reduced the concentration of phenol hydroxyl group, leading to the drying time of CF-Si to reduce to 25 min and the remarkable improvements of physico-mechanical properties. When the ratio of amount of substance of CF to DMS was 12.5 :3 and the reaction time was 25 rain, the hardness of CF-Si was 2 H, adhesion was two, glossiness was 128%, impact resistance was 45 cm, flexibility was 1 mm. CF-Si had excellent thermal stability. The weight loss rate of CF was twice than that of CF-Si at 400-500℃. When the explosure time of UV was 1400 h, the gloss loss of CF-Si was 27% while that of CF was 58%. The resistance against alkali of CF-Si was more remarkable than CF.

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期刊信息
  • 《福建师范大学学报:自然科学版》
  • 北大核心期刊(2011版)
  • 主管单位:福建师范大学
  • 主办单位:福建师范大学
  • 主编:余望
  • 地址:福州市福建师范大学旗山校区
  • 邮编:350117
  • 邮箱:linmin@fjnu.edu.cn
  • 电话:0591-22867857
  • 国际标准刊号:ISSN:1000-5277
  • 国内统一刊号:ISSN:35-1074/N
  • 邮发代号:34-43
  • 获奖情况:
  • 福建省优秀科技期刊,全国优秀高校自然科学学报,华东地区优秀期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),德国数学文摘,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:7294