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基于Pickering乳液的磁性高强水凝胶的制备及性能表征
  • ISSN号:1000-3304
  • 期刊名称:Gaofenzi Xuebao
  • 时间:0
  • 页码:-
  • 分类:O484.43[理学—固体物理;理学—物理]
  • 作者机构:[1]武汉理工大学材料科学与工程学院,武汉430070, [2]湖北师范学院污染物分析与资源化技术湖北省重点实验室,黄石435002
  • 相关基金:国家自然科学基金(基金号50973087)资助项目.
  • 相关项目:纳微米区域内选择性固定生物分子结构、取向和性能的研究
中文摘要:

合成了一种磁性Fe3O4纳米颗粒稳定的水包油(O/W)Pickering乳液并以其作为交联剂,在适宜条件下引发单体丙烯酰胺聚合来制备了一种新型的磁性高强复合水凝胶.采用x射线衍射(XRD)及场发射扫描电子显微镜(SEM)分别对磁性Fe3O4纳米颗粒和复合水凝胶的结构进行了表征,结果表明Pickering乳胶粒子较均匀地分布在复合凝胶网络中.溶胀性能测试及溶胀动力学分析表明复合水凝胶具有良好的溶胀性能,能够吸收自身干重100倍左右的水,其溶胀过程不遵循Fickian扩散模型;拉伸测试表明该水凝胶具有优异的力学性能,其拉伸强度能够达到150kPa左右,断裂伸长率能够达到300%左右,并且当其承受的应力释放后能快速地恢复到初始形态.磁性能测试的结果显示该水凝胶具有良好的磁性.

英文摘要:

A Fe304 nanoparticles-stabilized Pickering emulsion,which is a kind of emulsion stabilized by solid particles instead of traditional surfactants, was used as a cross-linking agent. And a novel composite hydrogel was prepared by initiating monomer acrylamide in the appropriate condition. The structure of nanopartieles and composite hydrogel was characterized through X-ray diffraction (XRD) measurements, and field-emission scanning electron microscope (SEM), respectively. Moreover, the properties of hydrogels were studied by swelling ability measurements and swelling kinetics analysis, mechanical test and magnetic response test. It can be found from SEM images that the TPM droplet acted as a cross-linking agent in the reactive system and distributed in the hydrogel network orderly. Swelling test indicated that the composite hydrogels had excellent swelling capacity in comparison to conventional hydrogels,and even could swell to about 100 times of their dry weight. And swelling kinetics analysis results showed that the swelling process of the composite hydrogels did not follow the Fickian swelling kinetics model. The mechanical test results showed that the composite hydrogel exhibited outstanding mechanical performance. The composite hydrogels showed a strength of 150 kPa and high elongation at break of 300%. Moreover,the composite hydrogels could return to original state after stretching to several times of its original length quickly and even could make into a knot without damage. Magnetic response test results indicated that the composite hydrogels exhibited a clear magnetic response.

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期刊信息
  • 《高分子学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院化学研究所
  • 主编:张希
  • 地址:北京市海淀区中关村北一街2号
  • 邮编:100190
  • 邮箱:gfzxb@iccas.ac.cn
  • 电话:010-62588927
  • 国际标准刊号:ISSN:1000-3304
  • 国内统一刊号:ISSN:11-1857/O6
  • 邮发代号:2-498
  • 获奖情况:
  • 国家优秀期刊二等奖,中科院优秀期刊二等奖,中国科协优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:19174