为研究Ti(C,N)基金属陶瓷在高温条件下的可应用性,采用XRD、SEM、EDS等方法分析了该陶瓷在900~1150℃的氧化行为及其机理。结果表明:在900~1150℃范围内,陶瓷氧化程度随氧化温度的升高而显著增加,其质量增加曲线近似呈抛物线形;在900℃空气中氧化100h后,陶瓷表面生成致密氧化膜(NiO+TiO2),厚度小于10μm,对基体具有保护作用;而在1150℃条件下,在致密层氧化膜(NiO+TiO2)表面衍生出岛状疏松层(TiO2),100h后厚度达80μm,氧化膜逐渐失去保护作用。
In order to research the applicability of Ti(C,N)-based cernlets at high temperatures. Oxidation behavior and mechanism at 900--1 150 ℃ of the lermet material were investigated by means of XRD, SEM, EDS. The results show that from 900 to 1 150℃, the oxidation degree obviously increased with the elevation of temperature, and the curves of gained mass were liner to parabola. After oxidation at 900 *C for 100 h in the air, thickness of the compact oxide layer generated on the surface of the material was less than 10 μm with composition of NiO+TiO2, which could protect the matrix. While on the condition of 1 150 ℃, loose layer with the main composition TiO2 derived from the inner compact one with thickness more than 80 μm, which lost the protection to matrix gradually.