位置：成果数据库 > 期刊 > 期刊详情页
Regioselective Ring-opening Reaction of 1,2-Epoxides with Arylselenol under Solvent-free Conditions and Application to the Synthesis of 1,3-Oxazolidin-2-ones
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 分类：O626[理学—有机化学;理学—化学] O621.25[理学—有机化学;理学—化学]
  • 作者机构：[1]State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China, [2]Department of Chemistry, Lishui College, Lishui, Zhejiang 323000, China
  • 相关基金：Project supported by the National Natural Science Foundation of China （Nos. 20472028, 20332050） and Education Commission of Zhejiang Province.
作者： 杨明华[1,2], 袁朝英[1], 潘毅[1], 朱成建[1]
关键词： 区域选择开链反应, 1, 2-环氧化物, 芳基硒醇, 溶剂自由反应, 钛异丙氧化物, 合成, 1, 3-氧氮杂环-2-酮, epoxide, arylselenol, solvent-free reaction, titanium isopropoxide, 1,3-oxazolidin-2-one
中文摘要：

有 ArSeH 的 1,2-epoxides 的 Regioselective 戒指洞反应由 Ti (OiPr ) 催化 4 在没有溶剂的条件下面被调查。许多 -hydroxyselenides 在 90%97% 和 regioselectivities 的优秀收益被获得由一简单，原子经济和环境友好的过程。几 N-tosyl-1,3-oxazolidin-2 一个被准备由一个一个壶从相应 1,2-epoxides 和 ArSeH 开始三步的过程。

英文摘要：

Regioselective ring-opening reactions of 1,2-epoxides with ArSeH catalyzed by Ti（O^tPr）4 under solvent-free conditions were investigated. A variety of β-hydroxyselenides were obtained in excellent yields of 90%-97% and regioselectivities by a simple, atom economic and environment-friendly procedure. Several N-tosyl- 1,3-oxazolidin-2-ones were prepared starting from the corresponding 1,2-epoxides and ArSeH by a one-pot three-step procedure.

同期刊论文项目
导向有机合成的杂原子化学
期刊论文 75 会议论文 7
软硬Lewis酸协同导引的不对称反应研究
期刊论文 20 会议论文 3
同项目期刊论文
Crystal Structure of Dimethyl
A Practical and Controllable E
Synthesis Characterization of
Chiral copper(II) Complexes of
A Facile Preparation of β-Flu
Formation of P-Ylide in a Neut
Highly Enantioselective α-Ami
First Application of Ionic Liq
Enantioselective Formal [3+3]
1,3,7,7-Tetramethylspiro[bicyc
An Efficient and Practical Syn
Phosphine-Catalyzed Intramolec
N-heterocyclic carbene catalyz
Addition of Benzyltrimethylsil
A Facile Reaction of Imines wi
Efficient Asymmetric Oxidation
The Michael Addition-Eliminati
Highly Stereoselective Synthes
Synthesis of alpha-phenylselen
Synthesis of C2-Symmetric Sulf
Me3Ga-mediated alkynylation of
(1R,2R)-(+)-1-(2-Hydroxybenzyl
Highly Enantioseletive Biginel
Sidearm effects in the enantio
Tetrahydrothiophene-Catalyzed
An Unexpected Tandem Ylide Ann
Enantioselective Pinacol Coupl
Asymmetric Synthesis of Chiral
Pseudo-C3-Symmetric Trisoxazol
(R,R)-N, N’-Bis(5-chlorosalic
Diastereoselective Tandem Mich
A New and Highly Efficient Asy
Olefination of Ketenes for the
Selectivity-controllable Ylide
An Efficient Ring-Opening Reac
An Efficient and Highly Regios
Telluronium and Sulfonium Ylid
The Synthesis of New C2-Symmet
PPh3-catalyzed ylide cyclizati
Highly Enantioselective and Di
New Camphor-derived Selenonium
Syntheses and solid state stru
Scandium triflate catalyzed cy
The first asymmetric addition
A Mild and Convenient Procedur
Controllable Enantioselective
Enantioselectively Organocatal
Regioselective Ring-Opening Re
Synthesis and Characterization
The development and applicatio
Iron Porphyrin-catalyzed Olefi
Ir-catalyzed regio- and enanti
WO3/salan/30%H2O2: a heterogen
Enantioselective synthesis of
手性Salen及Ga(Salen)催化苯基锂对环氧环己烷对映选择性开环反应
Crystal Structure of Dimethyl[
Enantioselective ring opening
Utilization of organogallium a
Anion-Directed Self-Assembly o
Synthesis of beta-hydroxyl sel
Synthesis of Chiral Calixarene
氯化锌催化硒酚对环氧化合物开环反应合成β-羟基硒醚
小分子胺直接有效催化合成α-苯硒基酮
期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175