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中文摘要：
合成了两种新型的有机正极材料——5-氨基-2,3-二氢-1,4-二羟基蒽醌（ADDAQ）和5-氨基-1,4-二羟基蒽醌（ADAQ）,用核磁氢谱（1H-NMR）、质谱（MS）、元素分析（EA）、傅里叶红外（FTIR）光谱、紫外-可见（UV-Vis）光谱等方法对材料进行了表征,应用恒流充放电（GD/C）、循环伏安法（CV）、交流阻抗（EIS）等测试手段对材料的电化学性能进行了测试.实验结果表明：相比ADDAQ,ADAQ首次放电容量和循环性能都有显著提高.ADAQ的首次放电比容量为185mAh·g-1,50次循环之后容量为93mAh·g-1.并讨论了ADDAQ和ADAQ电化学性能差异的原因.
英文摘要：
Two novel organic compounds,5-amino-2,3-dihydro-1,4-dyhydroxy anthraquinone（ADDAQ） and 5-amino-1,4-dyhydroxy anthraquinone（ADAQ）,were synthesized as cathode materials for lithium batteries.The compounds were characterized by 1 H nuclear magnetic resonance（ 1 H NMR）spectroscopy, mass spectrometry（MS）,elemental analysis（EA）,Fourier transform infrared spectroscopy（FTIR）, ultraviolet-visible（UV-Vis）spectroscopy.The electrochemical performance of the compounds was investigated by galvanostatic discharge/charge（GD/C）measurements,cyclic voltammetry（CV）,and electrochemical impedance spectrum（EIS）.Compared with ADDAQ,the initial discharge specific capacity and cycle performance of ADAQ were effectively improved.The initial discharge specific capacity of ADAQ was 185 mAh·g -1 ,after 50 cycles,the specific capacity was maintained at 93 mAh·g -1 .A reason for this improvement is discussed.
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