利用传统的电子陶瓷工艺制备了(1-x)(K0.54Na0.46)NbO3-xLiSbO3[(1-x)KNN-xLS]无铅压电陶瓷,研究了LiSbO3对(KNN-xLS陶瓷的相结构与介电压电性能的影响.研究结果表明,(1-x)KNN-xLS陶瓷的准同型相界位于0.04〈x〈0.06;(1-x)KNN-xLS陶瓷的电学性能强烈地依靠化学成分,在准同型相界附近具有加强的电学性能;(1-x)KNN-xLS0=O.05)陶瓷的室温压电常数达220pC/N,径向机电耦合系数达43%,居里温度为368℃,正交.四方转变温度为90℃,介电常数为l145,介电损耗为2.8%,剩余极化值为26.6p.C/cm^3,矫顽场为13.8kV/cm.因此可以认为,该陶瓷体系是具有应用前景的无铅压电陶瓷材料之一.
Lead-free piezoelectric ceramics (1-x)(K0.54Na0.46)NbO3-xLiSbO3 [(1-x)KNN-xLS] were prepared by ordinary sintering. A morphotropic phase boundary (MPB) between orthorhombic and tetragonal phases was identified in the composition range of 0.04〈x〈0.06. The ceramics near the MPB exhibit a strong compositional dependence and enhanced piezoelectric properties. It is found that the samples with 5 tool% LS exhibit enhanced electrical properties: the piezoelectric constant d33-220pC/N, the electromechanical coupling coefficient kp-43%; the Curie temperature Tc-368℃; the orthorhombic-tetragonal phase transition To-t=90℃; the remnant polarization Pr-26.6 μC/cm^2; the coercive field Ec-13.8 kV/cm. These results show that (1-x)KNN-xLS is a promising lead-free piezoelectric material.