采用多种色谱分离技术首次从石豆兰属植物芳香石豆兰中分离了13个化合物,这些化合物经波谱方法鉴定为:moscatin(1),3,7-dihydroxy-2,4-dimethoxyphenanthrene(2),2,7-dihydroxy-3,4-dimethoxyphenanthrene(3),2,5-dihydroxy-4-methoxy-9,10-dihydrophenanthrene(4),ephemeranthol-A(5),3,7-dihydroxy-2,4-dimethoxy-9,10-dihydrophenanthrene(6),2,4-dihydroxy-7-methoxy-9,10-dihydrophenanthrene(7),coelonin(8),rotundatin(9),4',5-dihydroxyl-3,3'-dimethoxybibenzyl(10),moscatilin(11),batatasinⅢ(12),tristin(13).其中化合物5,6,7和9首次从石豆兰属植物中分离得到.
The chemical constituents of BulbophyUum ambrosia were studied and 13 compounds were isolated by the method of silica gel and Sephadex LH-20 column chromatography. Their structures were identified as moscatin ( 1 ), 3,7-dihydroxy- 2,4-dimethoxyphenanthrene ( 2), 2,7-dihydroxy- 3,4-dimethoxy-phenanthrene ( 3 ), 2,5 -dihydroxy-4-methoxy-9,10-dihydrophenanthrene ( 4 ), ephemeranthol-A ( 5 ), 3,7 -dihydroxy -2,4 -dimethoxy-9,10-dihydrophenanthrene ( 6), 2,4-dihydroxy-7-methoxy-9,10-dihydrophenanthrene ( 7), coe- lonin (8), rotundatin (9), 4', 5 - dihydroxyl - 3,3' - dimethoxybibenzyl (10), moscatilin ( 11 ), batatasin Ⅲ (12) ,and tristin (13) on the basis of spectral analysis.Among them,compounds 5,6,7 and 9 were isolated from Bulbophyllum for the first time.