在电解液中加入不同含量的催化剂,研究了一维聚硫杂酞菁铁[P(FePcS2)]对锂/亚硫酰氯(Li/SOCl2)电池的催化作用。P(FePcS2)含量为1.0 g/L的电池以15 mA/cm2的电流密度放电,在25℃、55℃及-40℃时的电压分别提高约120mV、122 mV和230 mV,容量分别提高约1.30 Ah、0.60 Ah和0.55 Ah。
Catalysis of 1-D polymers of iron thiaphthalocyanine [P(FePcS2)] to the lithium/thionyl chloride (Li/SOCl2) cell was studied by adding different content of catalyst into electrolyte.When discharged with the current density of 15 mA/cm2 at 25 ℃,55 ℃ and-40 ℃,the voltage of cell with P(FePcS2) content of 1.0 g/L increased about 120 mV,122 mV and 230 mV,respectively,the capacity increased about 1.30 Ah,0.60 Ah and 0.55 Ah,respectively.