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页岩油窄馏分性质表征及其催化裂化性能研究
  • ISSN号:1005-2399
  • 期刊名称:《石油炼制与化工》
  • 时间:0
  • 分类:TE624.2[石油与天然气工程—油气加工工程]
  • 作者机构:中国石油大学华东重质油国家重点实验室,山东青岛266580
  • 相关基金:国家自然科学基金项目(U1462205和21476263);中央高校基本科研基金项目(13CX05002A);研究生创新工程的资助项目(YCX2015028).
中文摘要:

通过实沸点蒸馏装置按组分沸点将抚顺页岩油切割成5个窄馏分,测定每个馏分元素组成、残炭、碱性氮含量等基本性质;又利用红外光谱和’H—NMR谱图,通过昏L法计算各馏分的平均结构参数;再通过GC-MS对各馏分饱和分、芳香分的组成进行定性定量分析;最后考察随馏分沸程升高其催化裂化性能的变化。结果表明:随馏分沸程升高,其密度、残炭增大,页岩油氮元素及碱氮含量均远高于常规原油;且馏分越重,其芳碳率、侧链平均长度越大,三环及以上稠环芳烃所占比例越大;此外,较重馏分催化裂化结焦严重,但较轻馏分裂化反应的产物分布较为理想,说明页岩油具有催化裂化/JOT.潜力。

英文摘要:

Shale oil was separated into five narrow-cuts by true boiling point distillation. The prop- erties of the narrow-cuts, including elemental composition, carbon residue and basic nitrogen content, were tested. Base on the characterizations of infrared spectrometry and nuclear magnetic resonance, the average structure parameters of the narrow-cuts were calculated using Brown-Ladner method. The con- tents of saturate and aromatics in each narrow-cut were quantitatively measured. And the comparative evaluations were set to investigate the catalytic cracking performance of different narrow-cuts. The results show that as the boiling range of narrow-cut rises, the density and carbon residue increases, and the contents of both nitrogen and basic nitrogen in shale oil are higher than conventional crude oils. It is found that the heavier the narrow-cut, the higher the aromatic ratio and the longer the average length of side chain, and the larger ratio of condensed aromatics with three rings and above. Although the crack- ing of heavy narrow-cut leads to severe coking, the product distribution of light narrow-cuts is reasona- ble, indicating that shale oil has a potential for catalytic cracking processing.

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期刊信息
  • 《石油炼制与化工》
  • 中国科技核心期刊
  • 主管单位:中国石油化工集团公司
  • 主办单位:中国石油化工股份有限公司 石油化工科学研究院
  • 主编:汪燮卿
  • 地址:北京市海淀区学院路18号
  • 邮编:100083
  • 邮箱:sylz.shky@sinopec.com
  • 电话:010-82368292
  • 国际标准刊号:ISSN:1005-2399
  • 国内统一刊号:ISSN:11-3399/TQ
  • 邮发代号:2-332
  • 获奖情况:
  • 首届中国期刊奖,第二届全国优秀科技期刊一等奖,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13290