中文摘要：

通过以不同浓度盐酸对页岩油中的碱性氮化物进行分离及定量添加碱氮模型化合物的方法，辅以高分辨质谱对不同样品中碱性氮化物的结构进行表征，研究了页岩油中碱性氮化物对其裂化反应的阻滞作用。结果表明：页岩油中碱性氮化物主要为带烷基侧链的吡啶、环烷基吡啶，而且盐酸浓度越高，所富集出的碱性氮化物类型越多；碱性氮化物的去除有利于页岩油催化裂化反应的发生，且除含量外，碱性氮化物的结构对页岩油裂化过程也存在较大的影响，相对分子质量越大、缩合程度越高的碱性氮化物越不利于页岩油催化裂化反应的进行。

英文摘要：

The basic nitrogen compounds in shale oil were separated using HCI solutions with different concentrations, and the structures of separated compounds were characterized by ESI FT ICR MS technique. The retardation effect of the separated basic nitrogen compounds and model nitrogen compound added into the separated compounds on shale oil catalytic cracking was studied. The results showed that the basic nitrogen compounds were mainly pyridine and naphthenic pyridine with alkyl side