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铈掺杂对钙铋钛铁电陶瓷取向及性能的影响
  • 期刊名称:稀有金属材料与工程
  • 时间:0
  • 页码:263-265
  • 语言:中文
  • 分类:O482[理学—固体物理;理学—物理]
  • 作者机构:[1]山东建筑大学,山东济南250101
  • 相关基金:国家自然科学基金项目(50872075);山东省自然科学基金项目(Y2007F36)
  • 相关项目:环境友好型高取向织构化铁电压电陶瓷的制备及机理研究
中文摘要:

用固相烧结工艺,制备了不同Ce掺量CaBi4xCexTi4O15的陶瓷样品。用X射线衍射对其显微结构进行了分析,并测试了样品的介电、铁电性能,研究了烧结温度对样品晶粒取向和铁电性能的影响。结果发现Ce掺杂未改变CaBi4xCexTi4O15的晶体结构,1150℃烧结所得样品中a轴取向晶粒较多,有利于样品的铁电性能;x=0.2为最佳掺量,样品剩余极化强度最大,2Pr=18.4μC/cm^2,对应的矫顽场强度2Ec=99kV/cm,相对介电常数εr=165,介电损耗tanδ=2×10^-3。

英文摘要:

Ceramic samples CaBi4-xCexTi4O15(x=0, 0.05, 0.1, 0.15, 0.2, 0.25) were prepared by solid-state reaction method. Their structure was analyzed by X-ray diffraction, and their dielectric and ferroelectrics properties were measured. It is found that Ce-doping does not change the crystal structure of CaBi4Ti4O15. The remnant polarization (2Pr) increases at first but then decreases with the increase of Ce content. The 2Pr reaches a maximum value of 18.4 μC /cm^2 when x=0.2. The coercive field of CaBi3.8Ce0.2Ti4O15 is 99 kV/cm. The dielectric and dielectric loss of CaBi3.8Ce0.2Ti4O15 are 165 and 2×10^-3 measured at 100 kHz, respectively. Effects of different sintering temperatures on the crystal orientation of the CaBi3.8Ce0.2Ti4O15 ferroelectric ceramics were also studied. It is found that crystals developed entirely and a-axis orientation was enhanced at 1150 ℃.

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