采用室温液相陈化法制备了复合WO,的MoO3粉体,利用XRD、XPS、UV—Vis和PL光谱对合成产物进行了表征,以太阳光为光源对有机染料结晶紫进行了光催化降解研究。UV—Vis漫反射光谱和PL光谱分析结果表明,适量WO3的复合,能够改善MoO3对光的吸收,降低MoO3的PL光谱强度;当WO3复合量为5%时,复合物的PL光谱强度最低,结晶紫溶液的脱色率为89.12%,COD去除率为87.2%。
WO3/MoO3 powders were successfully prepared by the chemical ageing method. The products were characterized via X -ray powder diffraction (XRD), X -ray photoelectron spectroscopy( XPS), UV -Vis diffused reflectance spectrum(DRS) and photoluminescence( PL ) spectrum. The photocatalytic activity of WO3/MoO3 com- posites was evaluated by monitoring the degradation of crystal violet under sunlight irradiation. The results showed that the decoloration rate of crystal violet with 5% WO3/MoO3 product might reach 89.12% and the removal rate of chemical oxygen demand (COD) is 87.2%. UV -Vis light absorption of WO3 / MoO3 composite with different amounts of WO3 was enhanced. The intensity of PL spectrum was different with the WO3 amount of WO3/MoO3 product. When the mole ratio of WO3 was 5%, the intensity of PL spectrum of WO3 / MoO3 was the lowest, the rate of photocatalytic degradation for crystal violet was the highest.