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Cu2O/Bi2MoO6耦合系统增强光催化活性研究
  • ISSN号:1000-2162
  • 期刊名称:《安徽大学学报:自然科学版》
  • 时间:0
  • 分类:O614[理学—无机化学;理学—化学] O643.3[理学—物理化学;理学—化学]
  • 作者机构:安徽大学化学化工学院,安徽合肥230601
  • 相关基金:Supported by the Chinese National Science Foundation (21171002), the Natural Science Foundation of Anhui Province (11040606M55) and the Foundation of Education Committee of Anhui Province (KJ2010A015)
中文摘要:

采用乙二醇为溶剂,成功合成了耦合系统Cu2O/Bi2MoO6,分别采用X射线衍射(XRD)、拉曼光谱(Raman)、X射线光电子能谱分析(XPS)和透射电子显微镜(TEM)进行表征.样品的光催化活性通过在可见光下降解结晶紫来获得.结果表明,当Cu与Mo摩尔比为0.08,Cu2O/Bi2MoO6展示出最高的光催化性能,仅在100Min结晶紫的降解率达到95.6%.同时,研究了耦合系统中Cu2O的量对其光催化活性的影响,并提出了合理的反应机制.

英文摘要:

A coupled system of Cu2O/Bi2MoO6 with enhanced visible-light photocatalytic activity was successfully synthesized using ethylene glycol (EG) as a solvent. The as- synthesized samples were characterized via X-ray power diffraction (XRD), Raman spectrum, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and UV-Vis diffuse reflection spectrum (DRS) in detail. The photocatalytic activities of the synthesized samples were evaluated by monitoring the degradation of crystal violet solution under visible light. As a result, the obtained Cu20/Bi2MoO6 with the mole ratio of Cu/Mo 0.08 exhibited the excellent visible-light-driven photocatalytie performance, and the degradation ratio of crystal violet could reach 95.6% within 100 min. The effects of the amount of cuprous oxide on the catalytic activity of Cu20/Bi2 MoO6 were investigated. The possible reaction mechanism of this system was proposed.

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期刊信息
  • 《安徽大学学报:自然科学版》
  • 中国科技核心期刊
  • 主管单位:安徽省教育厅
  • 主办单位:安徽大学
  • 主编:罗斌
  • 地址:安徽合肥
  • 邮编:230039
  • 邮箱:adxbna@ahu.edu.cn
  • 电话:
  • 国际标准刊号:ISSN:1000-2162
  • 国内统一刊号:ISSN:34-1063/N
  • 邮发代号:26-39
  • 获奖情况:
  • 安徽省高校优秀学报一等奖,安徽省优秀科技期刊,省科委优秀期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),美国数学评论(网络版),德国数学文摘,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:4848