本文基于八氰基合钼(Ⅴ)阴离子和稀土GdⅢ离子合成了一种4d-4f双金属配合物,并进行了结构和磁性的研究。结果表明:配合物为一维亚铁磁链。
A 4d-4f bimetallic one-dimensional chain based on anionic octacyanidomolybdate(V) and rare earth GdⅢ ion has been synthesized and characterized structurally and magnetically, indicating that the complex is a ferrimagnetic chain. CCDC: 658854.