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中文摘要：
合成了{[M（L）2（H2O）2]（ClO4）2·4H2O}n（M=Cu1，Co2；L=1，4-二氮杂二环【2．2-2】辛烷-1，4-二乙酸），并进行了元素分析、红外、热重、变温磁化率等表征。单晶结构表明这2个配合物属于单斜晶系，P21／c空间群。Cu（Ⅱ）和Co（Ⅱ）均为六配位，八面体构型，每个金属离子与4个配体和2个水分子配位，每个配体采取附桥联模式，形成二维层状结构。磁性研究结果显示配合物1中Cu（Ⅱ）离子之间存在弱的反铁磁相互作用．配合物2中Co（Ⅱ）离子处于中等强度的配位场。
英文摘要：
Two coordination compounds, {[M（L）2（H2O）2]（ClO4）2-4H2O}n （M=Cu 1, Co 2; L=1,4-diazoniabicyclo[2.2.2] octane-1,4-diacetate）, were synthesized and characterized by elemental analysis, IR, TGA and magnetic susceptibilities. Single-crystal structures show the two compounds both crystallize in monoclinic system, space group P21/c. Cu（Ⅱ） and Co（Ⅱ） ions are coordintated with six oxygen atoms from two water molecules and four ligands to form an octahedral geometry. Each ligand links two metal ions in a/.tz-bridge coordination mode and two-dimensional wavelike structures are formed. Magnetic studies showed that weak antiferromagnetic interactions existed between the Cu（Ⅱ） ions in 1, and Co（Ⅱ） ions were located in a moderate ligand field in 2. CCDC： 684712, 1; 684713, 2.
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