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中文摘要：
以含2p，3d，4d，4f电子的分子/离子为自旋载体，选择合适的桥基进行化学组装，设计并合成了系列同金属或混合金属簇合物、链状化合物、层状和多孔化合物。得到了大量结构新颖的配合物，研究了反应条件对产物结构的影响与结构调控因素；深入研究了产物的磁学性质，通过理论模型与实验结果的对比探讨磁-构关系；获得了一系列过渡金属分子磁体、稀土金属分子磁体和异自旋分子磁体，其中稀土金属与自由基单分子磁体、八氰基三维磁体、表现出单分子磁体性质的有机膦酸锰簇合物和立方烷状结构的四核稀土-过渡金属簇合物等在结构和磁性上均具有显著特点；利用聚乙烯吡咯烷酮作为高分子基质合成了具有规则纳米结构的自旋转换金属高分子复合纳米薄膜材料，提出了新的规范高分子微观结构和自旋转换配合物功能化的方法；此外还获得了与磁性有关的新型分子手性材料和分子荧光材料。以上这些工作均发表在国际有影响的学术刊物上，为寻找有意义的单分子磁体、量子自旋体系和多功能分子基磁性材料提供了基础。
结论摘要：
英文主题词molecule-based magnets; magnetic materials; spin-crossover; complex; multi-function
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期刊论文
Three novel octacyanomolybdate(IV)–M(II) [M = Mn and Cu] bimetallic assemblies: crystal structures a
A New Bimetallic Ferrimagnet {[Mn2II(H2O)2(CH3COO)][MoV(CN)8] ?2H2O}n and Its Antiferromagnetic Anal
A peculiar heterotrimetallic MnII–CoII–NiII complex: Synthesis, crystal structure and magnetic prope
Nature of the LnIII-CoII Magnetic Interactions in Compounds [Ln2Co3(C5H4NPO3)6]·4H2O with Open-frame
Tetranuclear Clusters Containing a CrIII-Doped MnIII4O2 Core: Syntheses, Structures and Magnetic Pro
Template Synthesis of Lanthanide (Pr, Nd, Gd) Coordination Polymers with 2-Hydroxy- nicotinic Acid E
Zinc 4-Carboxyphenylphosphonates with Pillared Layered Framework Structures Containing Large 24-memb
A four-spin ring with alternating magnetic interactions formed by pyridine-substituted nitronyl nitr
Synthesis, Structures and Magnetic Proper ties of Coordination Compounds Based on 1,4-diazoniabicycl
Synthesis, crystal structure and magnetic properties of a dinuclear manganese(III) tetradentate Schi
Syntheses, Structures and Magnetic Properties of Cyanide-bridge Tetranuclear Clusters Containing [Ni
Novel 4d-4f bimetallic ferrimagnetic 1D chain {[Gd-III(DMF)4(MeOH)2][Mo-V(CN) 8]}n: Crystal structur
Unprecedented 7-connected 36×413×62 structural topology: Praseodymium-based coordination polymers bu
Anions-Directed Metal-Mediated Assemblies of Coordination Polymers Based on the Bis(4,4′-bis-1,2,4-t
Three types of heterometallic structural motifs based on [Mo(CN)8]3-/4- anion and MnII cation as bui
Four New Lanthanide-Nitronyl Nitroxide (LnIII = PrIII, SmIII, EuIII, TmIII) Complexes and a TbIII Co
The self-assembly of a heteronuclear complex monitored with ESI-MS and fluorescence spectrophotometr
Synthesis, structural, and magnetic properties of a supramolecular assembly constructed from radical
Structural Variations Influenced by Ligand Conformation and Counteranions in Copper(II) Complexes wi
Structure and magnetic properties of a novel heterospin 1-D chain complex containing both Cu(II) and
Self-Assembly of a Series of Metal-Organic Frameworks Based on 4-Pyridyl-1,2,4-triazole and Copper(I
Lanthanide Carboxyphosphonates Ln (O3PCH2-NC5H9-COO)(H2O)2 × xH2O with Open Framework Structures Con
Amino acid template-synthesis and characterization of three-dimensional metal phosphate/phosphite ne
Out-of-plane dimeric MnIII quadridentate Schiff-base complexes: Synthesis, structure and magnetic pr
Two [Au(CN)2]- bridged heterometallic coordination polymers directed by different 2, 2’ -bipyridyl-l
A new two-dimensional manganese(II) coordination polymer with alternating double end-on and single e
Eicosanuclear Cluster [Cu13W7] of Octacyanotungstate-Copper Bimetallic Assembly: Synthesis, Structur
Structure, spectroscopic, and magnetic properties of a new cobalt(II) complex with 5-sulfoisophthali
Metal Monophosphonates M {(2-C5H4NO)CH2PO3} (H2O)2 (M = Co, Ni, Mn, Cd): Synthesis, Structure, and M
A Ladder-like One-dimensional Chain Based on a New Biradical and CuII: Crystal Structure and Magneti
Three-dimensional Metal Phosphonodicarboxylates with GIS-zeolite Topology: Syntheses, Structures and
Efficient Synthetic Strategy to Construct Three-Dimensional 4f -5d Networks Using Neutral Two-Dimens
Manganese(II)-Octacyanometallate(V) Bimetallic Ferrimagnets with Tc from 41 to 53 K Obtained in Acid
Synthesis, structures and magnetic properties of a series of 3d -4f tetranuclear CoII2LnIII2 cubanes
Copper(I) Cyanide Coordination Polymers Constructed from Bis(Pyrazole-1-yl)alkane Ligands: Observati
Synthesis, Crystal Structures, and Magnetic Properties of MnII, CoII, and ZnII Coordination Polymers
Two tri-spin complexes based on gadolinium and nitronyl nitroxide radicals: Structure and ferromagne
Hydrolytic synthesis and structural characterization of five hexanuclear oxo-hydroxo lanthanide clus
Synthesis, Structures, Spectroscopy, and Magnetic Properties of Pyrazine-Bridged Two-Dimensional Com
A Novel Bimetallic Chain Based on [Mo(CN)8]3- and Yb3+ Ions as Building Blocks in Which Containing M
Carbonyl compound dependent hydrolysis of mono-condensed Schiff bases: A trinuclear Schiff base comp
Layered manganese and copper phosphonates with metamagnetism observed in Mn(2-pmp)(H2O)2·H2O (2-pmpH
Structure and magnetism of two heteropolynuclear complexes containing both macrocyclic and azido lig
Octacyanotungstate(V)-based square W 2M2 (M = Co, Mn) complexes: synthesis, structure and magnetic p
Systematic investigation of the lanthanide coordination polymers with γ-pyrone-2,6-dicarboxylic acid
Synthesis and Characterization of Three-Dimensional 3d-3d and 3d -4f Heterometallic Coordination Pol
Two trinuclear copper(II)-octacyanometalate(IV) bimetallic complexes coordinated with chiral ligands
Layered Cobalt(II) and Nickel(II) Diphosphonates Showing Canted Antiferromagnetism and Slow Relaxati
Three-dimensional 3d -4f polymers containing heterometallic rings: Syntheses, structures, and magnet
Microwave-assisted Hydrothermal Syntheses of Metal Phosphonates with Layered and Framework Structure
One-dimensional Copper Phosphonates Containing μ-Halide, μ-Pyridy N-oxide and Phosphonate Bridging L
Dimeric Nickel Phosphonates based on Bis(benzimidazol-2-ylmethyl)imino methylenephosphonate: Ni2(bbi
Two novel 3D 3d -4f polymers with triethylenetetraaminehexaacetic acid: Syntheses, structures, and m
Hydrothermal synthesis, crystal structure and fluorescence quenching of hexanuclear Ni5(II)Ln(III) c
Heteronuclear complexes of macrocyclic oxamide with co-ligands: Syntheses, crystal structures, and m
Tuned Triazolatesilver(I) Luminescent Complexes from Zero- to Three-Dimensionality Based on Bi- to T
Self-assembly of novel 3d-4d -4f heterometal-organic framework based on double-stranded helical moti
Homochiral Zinc Phosphonates with Layered and Open Framework Structures Using Polycarboxylate as Sec
Cobalt diphosphonate with a novel ladder-like chain structure exhibiting field-induced magnetic tran
1D chain lanthanide coordination polymers with 6-hydroxynicotinic acid: Crystal structures and lumin
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