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中文摘要：
合成了一个水杨醛-1，2-丙二胺Schiff碱锰（Ⅲ）单核配合物[Mn（salpn）（CH3OH）（4，4＇-bipy）]（BPh4）．单晶X-射线衍射结果表明，该配合物属单斜晶系，P2（1）／c空间群，晶胞参数a=1．3717（3）nm，b=2．6297（5）nm，c=1．3581（3）nm，α=90。，β=110．256（4）°，γ＝90°．配合物中，中心Mn（Ⅲ）离子采取畸变的八面体配位构型，4，4’-联吡啶和甲醇分子作为轴向端基配体与Mn（Ⅲ）离子配位，单核单元之间通过氢键作用构成了一维链状结构．
英文摘要：
A mononuclear Mn（ Ⅲ ） Schiff base complex [Mn（salpn） （CH3OH） （4,4＇-bipy）] （BPh4） has been synthesized. Single crystal X-ray analysis reveals that the complex belongs to monoclinic crystal system, P2（1）/c space group, unit cell dimensions a=1. 3717（3）, b= 2. 629 7（5）, c=1.358 1（3） nm, α=90°, β=110.256（4）°, γ=90°. The central Mn（Ⅲ） ion adopts a distorted octahedral geometry. 4,4＇-bipyridine and methanol act as axial terminal ligand coordinated with Mn（ Ⅲ ） ion. The mononuclear units are linked by hydrogen bonds into one dimensional chains.
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