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基于电纺丝法的In2O3/CdO复合材料的制备及甲醛气敏特性
  • ISSN号:1000-6818
  • 期刊名称:《物理化学学报》
  • 时间:0
  • 分类:O649[理学—物理化学;理学—化学]
  • 作者机构:[1]大连理工大学电子科学与技术学院,辽宁大连116023, [2]大连民族学院机电工程系,辽宁大连116600
  • 相关基金:国家自然科学基金(61176068,61131004,61001054)资助项目
中文摘要:

用静电纺丝法制备了In(NO3)3,聚乙烯吡咯烷酮(PVP)纺丝前驱物,然后分别在500、600、700℃时烧结得到三种In2O3纳米纤维.通过X射线衍射(XRD)仪、热重差热分析(TG/DTA)、场发射扫描式电子显微镜(FE.SEM)表征结果得知,500℃时In2O3的晶相已经形成,且粒径为最小,约为24nm,纳米纤维呈介孔结构.将三种烧结温度的In2O3纤维制作成气敏元件,测试对比了三种元件对甲醛气体的敏感特性,结果表明,500℃烧结得到的In2O3纳米纤维在工作温度为240℃时响应最好,对浓度为10×10^-6(体积分数,妒)甲醛的响应为7.用静电纺丝法合成了CdO纳米颗粒,通过XRD、SEM表征得知CdO呈粒径约为68nm的颗粒.将In2O2和CdO以不同摩尔比(1:1,10:1,20:1)复合,对比测试了纯In2O3及三种In2O3/CdO复合材料对应的气敏元件对甲醛的气敏特性,测试结果表明当In2O3纳米纤维与CdO纳米颗粒以摩尔比10:1复合时,元件的工作温度较低(200℃),且对甲醛表现出最佳的气敏特性,对浓度为10×10^-6甲醛的响应为13.6,响应/恢复时间为140s/32S.最后对不同摩尔比复合的In2O3/CdO对甲醛的气敏机理进行了初步分析.

英文摘要:

In(NO3)Jpolyvinyl pyrrolidone (PVP) nanofiber precursors were synthesized using a traditional electrospinning method, and were then annealed at 500, 600, and 700 ℃ to form In203 nanofibers. The as-prepared In203 nanofibers were characterized using X-ray diffraction (XRD), thermal gravimetry and differential thermal analysis (TG/DTA), and field-emission scanning electron microscopy (FE-SEM). The results show that the In2O3 nanofibers crystallize well, with a small average grain size (about 24 nm) and a good mesoporous structure, when annealed at 500 ℃. The In203 nanofibers annealed at the three temperatures were further used to fabricate gas sensors. The test results show that the sensor based on In203 annealed at 500℃ has the highest response (about 7) to 10x 10-~ (volume fraction, ℃) formaldehyde (HCHO) at an operating temperature of 240 ℃. CdO nanoparticles were also prepared using the same method; XRD and FE-SEM show that the average grain size of CdO is about 68 nm. Finally, the as-prepared In203 nanofibers were mixed with the as-prepared CdO in molar ratios of 1:1, 10:1, and 20:1, and the mixtures were used to fabricate gas sensors. The HCHO-sensing properties of the sensors based on pure In2O3 and In2O3/CdO composites with different molar ratios were investigated at each optimum temperature. The results show that the In2O3/CdO composite with a molar ratio of 10:1 has excellent sensing properties: the response to 10x 10-6 HCHO is 13.6, the response/recovery time is 140 s/32 s, and the selectivity is better at a lower operating temperature of 200 ℃. In addition, the HCHO-sensing mechanism of the sensors based on the In2O3/CdO composites was briefly analyzed.

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期刊信息
  • 《物理化学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京大学化学与分子工程学院承办
  • 主编:刘忠范
  • 地址:北京大学化学楼
  • 邮编:100871
  • 邮箱:whxb@pku.edu.cn
  • 电话:010-62751724
  • 国际标准刊号:ISSN:1000-6818
  • 国内统一刊号:ISSN:11-1892/O6
  • 邮发代号:82-163
  • 获奖情况:
  • 中文核心期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:24781