采用金属Cu为“牺牲阳极”,在含配体对甲苯磺酰L-异亮氨基酸(H2L)的甲醇溶液中电解合成了[Cu(L)(2CH3OH)]配合物.当向含配体的甲醇溶液中加入2,2’-联吡啶时,电解合成了[Cu(L)(2,2’-bipy)]配合物.利用元素分析、红外光谱、紫外光谱、热分析对配合物进行了表征.测试了铜电极在溶液中的电化学行为和配合物的电化学性质.
The direct electrosynthesis of Cu(Ⅱ)complexes of tosyl- L- isoleucine, methanol was accomplished by electrochemical dissolution of sacrificial copper anodes in a methanol solution. When 2, 2' - bipyr/dyl was added to the electrolyte solution a complex of ICu(L) (2,2' -bipy)] was obtained. The complexes were characterized by FT- IR, elemental analysis, UV- Visible spectra and thermal analysis. The electrochemical properties of the complexes and the electrochemical behaviors of metal electrode in electrolyte solution were examined.