中文摘要：

通过前驱体Ti（OEt）4直接水解和电化学扫描电沉积法制备在Ti基体上的纳米TiO2-碳纳米管复合膜载Pt（Pt／nanoTiO2-CNT）复合催化剂．透射电镜（TEM）和X射线衍射（XRD）结果表明，锐钛矿型纳米TiO2粒子和Pt纳米粒子（粒径均为5-10nm）均匀地分散在碳纳米管表面．通过循环伏安和计时电流法研究表明，Pt／nanoTiO2-CNT复合催化剂（Pt载量为0．32mg·cm^-2）具有高达51．8m^2·g^-1的电化学活性比表面积，常温常压下对乙醇的电化学氧化具有高催化活性和稳定性，乙醇氧化峰电位分别为0、59、0．96和0．24V，氧化峰电流密度分别达到-115、-113和-75mA·cm^-2．复合催化剂对乙醇电氧化的高催化活性可归因于nanoTiO2、CNT和Pt纳米粒子的协同催化作用．

英文摘要：

Pt/nanoTiO2-CNT complex catalysts were prepared by direct hydrolysis of Ti（OEt）4 and electrochemical scan electrodepositing method. The results of XRD and SEM showed that the nanoTiO2 （anatase） and Pt nanoparticles （size about 5-10 nm） were dispersed uniformly on CNT film surface. The electrocatalytic activity of Pt/nanoTiO2-CNT electrode was investigated by cyclic voltammetry and chronopotentiogram. The results indicated that Pt/nanoTiO2- CNT electrode （Pt loading was 0.32 mg·cm^-2） exhibited high electrochemical activity surface area （51.8 m2·g^-1） and very high electrocatalytic activity and stability for the electro-oxidation of ethanol at room temperature in atmosphere pressure. The oxidation peak potentials of ethanol were 0.59, 0.96, and 0.24 V, and the corresponding oxidation peak current sdensities were -115, -113, and -75 mA·cm^-2. The high electrocatalytic activity and good stability can be attributed to the synergistic catalytic effect among nanocomposite.