金刚石具有极高的硬度、热导率和良好的抗磨损性能,在钢铁基体表面沉积金刚石膜具有广阔的应用前景。本文对不同成分和组织钢铁基体化学气相沉积金刚石膜的影响因素进行了分析,指出了奥氏体→珠光体或奥氏体→马氏体转变引起的相变应力对金刚石膜粘附性能的负面影响;综述了钢铁表面化学气相沉积金刚石膜的国内外研究现状,指出了今后钢铁上沉积金刚石膜的发展方向。
The latest progress in surface modification of steel substrates with diamond coatings was tentatively reviewed. The diamond coatings on steel substrate have found increasingly wider applications because of its favorable mechanical properties, such as its extremely high hardness and wear resistance, low friction coefficient, and good thermal con- ductivity. The discussions centered on: i)two major problems in synthesis of diamond coatings by chemical vapor deposition(CVD), one is the catalytic effect of Fe, Ni, Co, and alloys on formation of graphitic carbon materials and the other is the poor interfacial adhesion because of release of stress and strain at the interface in the cooling induced phase transition from austenite to pearlite or austenite to martensite; ii)possible solutions including growth of a variety of composite transition multi-layers capable of blocking inter-diffusion of Fe, Ni, Co, C, and improving the interfacial adhesion; and iii) advanced technologies in synthesis diamond coatings on austenitic stainless steel and high alloy steel. The development trends in deposition of diamond coating on steel were also briefly discussed in a thought provoking way.