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电场对TiO2-C—Al系燃烧合成过程的影响
  • ISSN号:1000-3851
  • 期刊名称:《复合材料学报》
  • 时间:0
  • 分类:TB331[一般工业技术—材料科学与工程]
  • 作者机构:[1]华中科技大学塑性成形模拟及模具技术国家重点实验室,武汉430074, [2]江南大学机械工程学院,无锡214122
  • 相关基金:国家自然科学基金资助项目(50574042)
中文摘要:

以3TiO2+3C+(4+x)Al反应体系为对象,直接燃烧合成致密的TiC-Al2O3-Al复合材料。着重研究了电场对该体系燃烧合成过程的影响。结果表明:外加电场的焦耳热效应可提高体系的绝热燃烧温度,从而突破燃烧合成反应的热力学限制;电场可改变体系的燃烧合成反应的模式;随着电场强度的增加,自蔓延燃烧温度和速度均提高,而合成材料组织中Al2O3和TiC晶粒尺寸逐渐减小;当体系中过余Al量x为14mol、外加电场强度E为25V/cm时,可直接燃烧合成相对致密性为92.5%的TiC-Al2O3-Al复合材料,且合成的Al2O3和TiC晶粒尺寸细小(0.2~1.0μm),在金属Al中分布均匀。

英文摘要:

Taking 3TiO2+3C+(4+x)Al as a reaction system, a dense TiC-Al2O3-Al composite was directly prepared. The effect of electric-field on the combustion synthesis process of the system was systematically investigated. The results show that the imposition of an external electric field can improve the adiabatic temperature of the reactive system and induce its self-sustaining combustion synthesis process. The electric field also can change the combustion modes of the system. With an increase of the field strength, both the combustion temperature and the self-propagating wave velocity are increased obviously, while the grain size of the in-situ synthesized TiC and Al2O3 particles is decreased significantly. Under the conditions of the AI residual a: being 14 mol in the system and the electric field strength E being 25 V/cm, a dense TiC-Al2O3-Al composite with a relative density of 92.5 % can be successfully fabricated, in which TiC and Al2O3 particles have a fine size of 0.2-1.0 mm, and distribute uniformly in metal Al.

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期刊信息
  • 《复合材料学报》
  • 中国科技核心期刊
  • 主管单位:工业和信息化部
  • 主办单位:北京航空航天大学 中国复合材料学会
  • 主编:益小苏
  • 地址:北京海淀区学院路37号
  • 邮编:100083
  • 邮箱:
  • 电话:010-82316907
  • 国际标准刊号:ISSN:1000-3851
  • 国内统一刊号:ISSN:11-1801/TB
  • 邮发代号:80-413
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:17731