以天然纤维素纤维作为基体材料,通过Ce^4+引发的自由基聚合,在其表面接枝聚甲基丙烯酸二甲胺基乙酯,合成了阴离子吸附剂cellulose-g-PDMAEMA(纤维素接枝聚甲基丙烯酸二甲胺基乙酯),用于水中砷的去除。采用场发射扫描电镜(FE-SEM)、傅里叶变换红外光谱(FT-IR)及元素分析对材料进行表征。并且分别用静态吸附实验和动态吸附实验研究材料的吸附性能,结果表明,该阴离子吸附剂可以有效地吸附水中三价砷和五价砷。
In this study,the natural cellulose fibers are chosen as template and the anion adsorbent cellulose-g-PDMAEMA is synthesized for arsenic removal.The cellulose fibers were surface modified by graft-polymerization of (N,N-dimethyl aminoethyl methacrylate) (DMAEMA) initiated by Ce4+.The adsorbent was characterized by Field Emission Scanning Electron Microscopy (FE-SEM),Fourier Transform Infrared Spectroscopy (FT-IR) and elemental analyzer.And the adsorption behavior was evaluated by both batch and column experiments.The results indicate that the adsorbent has a high efficiency in the removal of arsenite and arsenate from aqueous solutions.