中文摘要：

采用水热法在掺氟的 SnO2透明导电玻璃（FTO）基底上制备了金红石型的TiO2纳米棒阵列；然后采用电化学方法在 TiO2纳米棒阵列上沉积不同厚度的CdSx Se1－x纳米晶，形成了CdSx Se1－x纳米晶包覆TiO2纳米棒的 CdSx Se1－x/TiO2壳核结构；利用扫描电镜（SEM）、能谱分析（EDS）、X射线衍射（XRD）、紫外-可见漫反射吸收光谱（UV-Vis DRS）等对其形貌、结构组成等进行了分析和表征，结合循环伏安法及其吸收光谱确定了CdSx Se1－x纳米晶的能级位置.最后以P3 HT/CdSx Se1－x/TiO2复合薄膜材料为光活性层组装成固态纳米结构杂化太阳电池，研究了 CdSx Se1－x壳层厚度对该电池光电转换性能的影响，结果表明转换效率最高可达到0．68％.

英文摘要：

In this work,vertically aligned rutile TiO2 nanorod arrays were prepared on the fluorine-doped SnO2 transparent conducting glass oxide （FTO）by a hydrothermal method.The CdSx Se1-x nanocrystals were elec-trochemically deposited into the TiO2 nanorod array to form the CdSx Se1-x/TiO2 shell-core nanorod array struc-ture.Scanning electron microscopy （SEM）,X-ray diffraction （XRD）microscopy,energy dispersive-ray spec-troscopy （EDS）and ultraviolet-visible diffuse reflection spectrum （UV-Vis DRS）were used to study the mor-phology,crystal structure and composition of the samples,respectively.The hybrid solar cells with the de-signed （P3 HT）/CdSx Se1-x/TiO2 shell-core nanostructures were fabricated.As a result,the hybrid solar cell based on the （P3HT）/CdSx Se1-x （9min）/TiO2 photoelectrode exhibitied an energy conversion efficiency of 0.68%.