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中文摘要：
用对氯苯甲醛和对羧基苯甲醛为原料，合成了周边含羧基苯基的不对称卟啉中间体，然后再与5．氟尿嘧啶反应，合成了两种亚烷基链长不同的标题化合物，产率为22．1％和19．8％。产物结构由元素分析、红外光谱、紫外可见光谱、核磁共振谱和质谱表征确认。同时对目标化合物的合成条件进行了研究，结果表明，在以DMF为溶剂、反应温度在125℃、反应时间8h条件下，反应产率较高。
英文摘要：
Using p-chlorobenzaldehyde and p-carboxylbenzaldehyde as the starting materials, the porphyrin intermediate containing carboxyphenyl in peripheral was synthesized, then it was reacted with 5-fluorouracil, the titled compounds with different alkylene length were synthesized with yields 22.1% and 19.8%, respectively. The structures of the products were characterized by elemental analysis, UV-Vis, IR, ^1 H NMR and MS. The results showed that the yield was higher when DMF was used as the solvent at 125℃ for 8h.
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