中文摘要：

合成了锌（Ⅱ）与3,4．吡啶二羧酸和1，10-邻菲哕啉形成的配位聚合物[Zn（PDC）（phen）]。（1）（H2PDC=3，4-吡啶二羧酸，phen=1，10-邻菲哕啉），对其进行了元素分析、红外光谱和X射线单晶衍射表征，测定了晶体结构．该聚合物属单斜晶系，P2（1）／n空间群，a=0．77136nm，6=1．9757（4）nm，c=1．0680（2）nm，β=95．36（3）°，y=1．6205（6）nm^3，Z=4，Dc=1．683Mg／m^3，Mr=410．68，F（000）=832，μ=1．55mm^-1，最终偏离因子R1=0．0608，wR2=0．0967．该化合物中Zn原子与来自两个PDC的三个羧基氧原子，另外一个PDC的吡啶氮原子，以及phen的两个氮原子配位，形成的ZnN3O3八面体通过PDC桥联形成二维层状网络结构．此外还研究了该聚合物的热性质和荧光性质．

英文摘要：

Zinc（Ⅱ） pyridine-3,4-dicarboxylate polymeric complex with phen, [Zn（PDC）（phen）], （H2PDC = pyridine-3,4-dicarboxylic acid, phen=1,10-phenthroline） has been synthesized and characterized by means of elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group P2（1）/n with a=0.77136 nm, b= 1.9757（4） nm, c=1.0680（2） nm, f1=95.36（3）°, V= 1.6205（6） nm^3, Z=4, Dc= 1.683 Mg/m3, Mr=410.68, F（000）=832,μ= 1.55 mm^-1 and R1 =0.0608, wR2= 0.0967. The X-ray analysis revealed that the central Zn atom is octahedrally coordinated by three O atoms from two PDC ligands, one N atom from another PDC and two N atoms from phen. The resulting ZnN3O3 octahedron is bridged by PDC, forming a 2D layer net structure. In addition, the thermal and luminescent properties of the title compound were also studied.