这份报纸论述新选择吸附物基于设计发生在底层的毛孔的典型反应把包含氮的杂环的混合物从模型和商业交通柴油移开。这反应吸附物由甲醛, phosphotungstic 酸和圣巴巴拉组成美国(SBA )-15。实验在批和改正床系统作为催化剂用 phosphotungstic 酸与甲醛基于包含氮的杂环的混合物的假定 hydroxymethylation 反应。在模型燃料的氮集中是 237.33 ng ?? ???? ???? 癥汵湩捩 ?????????? “
This paper presents a new selective adsorbent to remove nitrogen-containing heterocyclic compounds from model and commercial transportation diesel fuels based on characteristic reaction designed to occur in the pores of substrate.This reactive adsorbent is composed of formaldehyde,phosphotungstic acid and Santa Barbara USA(SBA)-15.The experiment was based on assumed hydroxymethylation reaction of nitrogen-containing heterocyclic compounds with formaldehyde using phosphotungstic acid as catalyst in batch and fixed-bed systems.The nitrogen concentration in the model fuel was 237.33 ng.μl-1,carbazole and toluene were used as model nitrogen-containing heterocyclic compound and solvent,respectively.The effectiveness of reactive adsorbent for removal of nitrogen-containing heterocyclic compounds from commercial 0# diesel fuel containing 224.86 ng.μl-1 nitrogen was examined in a fixed-bed reactor at 70 ℃.The results showed that nitrogen in the model fuel was very low and the nitrogen concentration in the commercial diesel reduced to 2.44 ng.μl-1.The demand for transportation fuel with ultra-low nitrogen is satisfied.