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Selective Removal of Nitrogen-Containing Heterocyclic Compounds from Transportation Diesel Fuels with Reactive Adsorbent
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:TQ536[化学工程—煤化学工程] X172[环境科学与工程—环境科学]
  • 作者机构:[1]College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China, [2]Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China
  • 相关基金:Supported by the National Natural Science Foundation of China(21006053);the Fundamental Research Funds for the Central Universities(65010551);the Research Funds of Humanistic Social Science for Cyclic Economy and Low-Carbon Developments(951004)
中文摘要:

这份报纸论述新选择吸附物基于设计发生在底层的毛孔的典型反应把包含氮的杂环的混合物从模型和商业交通柴油移开。这反应吸附物由甲醛, phosphotungstic 酸和圣巴巴拉组成美国(SBA )-15。实验在批和改正床系统作为催化剂用 phosphotungstic 酸与甲醛基于包含氮的杂环的混合物的假定 hydroxymethylation 反应。在模型燃料的氮集中是 237.33 ng ??  ???? ???? 癥汵湩捩 ?????????? “

英文摘要:

This paper presents a new selective adsorbent to remove nitrogen-containing heterocyclic compounds from model and commercial transportation diesel fuels based on characteristic reaction designed to occur in the pores of substrate.This reactive adsorbent is composed of formaldehyde,phosphotungstic acid and Santa Barbara USA(SBA)-15.The experiment was based on assumed hydroxymethylation reaction of nitrogen-containing heterocyclic compounds with formaldehyde using phosphotungstic acid as catalyst in batch and fixed-bed systems.The nitrogen concentration in the model fuel was 237.33 ng.μl-1,carbazole and toluene were used as model nitrogen-containing heterocyclic compound and solvent,respectively.The effectiveness of reactive adsorbent for removal of nitrogen-containing heterocyclic compounds from commercial 0# diesel fuel containing 224.86 ng.μl-1 nitrogen was examined in a fixed-bed reactor at 70 ℃.The results showed that nitrogen in the model fuel was very low and the nitrogen concentration in the commercial diesel reduced to 2.44 ng.μl-1.The demand for transportation fuel with ultra-low nitrogen is satisfied.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),英国高分子图书馆,日本日本科学技术振兴机构数据库,中国中国科技核心期刊
  • 被引量:385