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Carbon Dioxide Captured from Flue Gas by Modified Ca-based Sorbents in Fixed-bed Reactor at High Temperature
  • ISSN号:1004-9541
  • 期刊名称:《中国化学工程学报:英文版》
  • 时间:0
  • 分类:TQ051.14[化学工程] TQ116.3[化学工程—无机化工]
  • 作者机构:[1]College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China
  • 相关基金:Supported by the National Natural Science Foundation of China (21006053), the Fundamental Research Funds for the Central Universities (65010551) and Special Projects of Environmental Protection (2009ZX07208).
中文摘要:

四种 Ca-based 吸着剂被锻烧和水和反应用不同先锋准备:氢氧化钙,钙碳酸盐,钙醋酸盐一水化物和钙氧化物。那些吸着剂的 CO2 吸收能力在 350650 的温度范围在一个改正床反应堆被调查

英文摘要:

Four kinds of Ca-based sorbents were prepared by calcination and hydration reactions using different precursors: calcium hydroxide, calcium carbonate, calcium acetate monohydrate and calcium oxide. The CO2 absorption capacity of those sorbents was investigated in a fixed-bed reactor in the temperature range of 350-650 ℃. It was found that all of those sorbents showed higher capacity for CO2 absorption when the operating temperature higher than 450 ℃. The CaAc2-CaO sorbent showed the highest CO2 absorption capacity of 299 mg.g-1. The mor- phology of those sorbents was examined by scanning electron microscope (SEM), and the changes of composition before and after carbonation were also determined by X-ray diffraction (XRD). Results indicated that those sorbents have the similar chemical compositions and crystalline phases before carbonation reaction [mainly Ca(OH)2], and CaCO3 is the main component after carbonation reaction. The SEM morphology shows clearly that the sorbent pores were filled with reaction products after carbonation reaction, and became much denser than before. The N2 adsorption-desorption isotherms indicated that the CaAc2-CaO and CaCO3-CaO sorbents have higher specific surface area. lar2er oore volume and anoropriate pore size distribution than that of CaO-CaO and Ca(OH)2-CaO.

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期刊信息
  • 《中国化学工程学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国化学工业与化学工程学会
  • 主编:
  • 地址:北京东城区青年湖路13号
  • 邮编:100011
  • 邮箱:cjche@cip.com.cn
  • 电话:010-64519487/88
  • 国际标准刊号:ISSN:1004-9541
  • 国内统一刊号:ISSN:11-3270/TQ
  • 邮发代号:
  • 获奖情况:
  • 1998年化工系统优秀信息成果一等奖,中国期刊方阵“双效”期刊
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  • 被引量:385