中文摘要：

利用反相液相色谱-电喷雾-串联质谱法同时分析了水体中的6种邻苯二甲酸酯（DMP、DEP、DBP、DEHP、DOP和DNP）以及OP、NP和BPA。用Waters XTerra^TM MSC18色谱柱，乙腈和乙酸铵溶液作为梯度洗脱的流动相。结果表明，9种物质的分离效果良好，邻菲二甲酸酯采用亚离子模式检测，烷基酚采用负离子模式检测。通过多反应监测模式（MRM）对各目标物进行定量，检出限为0．1～1μg／L。该方法已用于北京某垃圾填埋场渗滤液中相关物质的检测，结果表明：原水中邻苯二甲酸酯和烷基酚的总浓度为218—291μg／L，其中主要是DEHP。垃圾渗滤液处理工艺对这些物质有明显的去除效果。

英文摘要：

A reversed-phase liquid chromatography-electrospray ionisation tandem mass spectrometric （LC-ESI/MS-MS） method was developed for the simultaneous determination of 6 phthalate esters dimehtylphthalate （DMP）, diethylphehalate （DEP）, dibutylphthalate （DBP）, di （2-ethylhexy）phthalate （ DEHP）, dioctylphthalate （DOP） and dinonylphthalaet （DNP） and alkylphenols （ octylphenol （ OP）, nonyphenol （NP） and bisphenol （BPA）） in aquatic environment in a single run. The analytes were separated on a Waters XTerraTM MS C18 column used a binary mobile phase gradient with 5 mmol/L ammonium acetate in water and acetonitrile. As a result, well-shaped peak can be obtained on the chromatogram of every analyte under the multi-reaction monitoring mode. Instrumental limits of detection for these compounds were 0. 1 - 1 μg/L. This method was applied to the analysis of the leachate from a landfill site in Beijing. Phthalate esters and alkylphenols were detected in all the raw leachate samples at a level of 218.2 - 290.7 μg/L, with the dominant of DEHP. Concentration of these compounds decreased significantly after the leachate treatment process.