中文摘要：

介孔材料在催化、吸附、分离等领域有潜在的应用价值。近来，研究人员将介孔材料的有序孔道作为聚合微反应器，在其内部进行了许多类型的聚合反应，如自由基聚合反应和非自由基聚合反应。本文综述了近二十年来在介孔材料孔道内各类单体进行的非自由基聚合反应，包括氧化聚合反应、配位聚合反应、缩合聚合反应、开环聚合反应和阳离子聚合反应，阐述了各种因素对聚合反应及其聚合产物性能的影响，初步探讨其应用领域，对其应用前景进行了展望。

英文摘要：

Mesoporous materials are potentially used in catalysis, absorption and separation. Lately, researchers applied the order channel of the material as microreaetor for monomer polymerization. Many polymerizations were carried out within the channel, including free radical polymerization and non-free radical polymerization. The latest 20 year＇s progress of the non-free radical polymerizations in the channel of mesoporous molecular sieve was reviewed. These polymerizations included the oxidative polymerization, coordination polymerization, condensation polymerization, ring- opening polymerization and ionic polymerization. composite were discussed. The application fields of overlooked. Some effects on the polymerization and polymer the obtained polymer/mesoporous composites were