中文摘要：

介孔材料具有孔道大小均匀、排列有序、高比表面积、孔径连续可调的特性，主要应用在催化、吸附、分离、传感器以及光、电、磁等许多领域。近年来，研究人员利用其空旷的孔道作为聚合“微反应器”，在其内部进行了许多类型的聚合反应。综述了近二十年来在介孔材料孔道内烯类单体进行的自由基聚合反应，包括常规的自由基聚合反应和活性聚合反应，讨论了所得聚合物和介孔材料／聚合物复合材料的性能，认为对其聚合反应机理和应用值得进一步研究。

英文摘要：

Mesoporous molecular sieves （MMS） have been used in many fields such as catalysis, absorption, separation and sensor along with optical, electrical and magnetic science, due to their uniform and order channel,large specific surface area and adjustable pore size. Recently,a lot of polymerizations were carried out in the channel of MMS, taking the advantage of their empty channels as the micro- reactor. The latest 20 years progress of the free radical polymerizations in the channel of MMS, including the regular free radical polymerization and active free radical polymerization were reviewed. The properties of the polymer and polymer/MMS composite were discussed. The polymerization mechanism and application need further investigated.