欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
采用索氏抽提、多层硅胶氧化铝柱分离净化和气相色谱质谱联用仪（GC-EI-MS和GC-ECNI-MS）分别对沉积物及土壤样品中的十溴二苯基乙烷（DBDPE）,四溴双酚A双（2,3-二溴烯丙基）醚（TBBPA-DB-PE）,1,2-双（2,4,6-三溴苯氧基）乙烷（BTBPE）3种新型溴代阻燃剂进行了定性和定量分析,并建立了环境样品中这3种新型溴代阻燃剂的检测方法.在3个流程空白中,所有目标物都低于检出限;加标空白中目标化合物DBDPE,TBBPA-DBPE,BTBPE的回收率分别为74.8%—82.5%,88.9%—100.7%,86.7%—102.3%.方法检出限分别为1ng.g-1,0.4ng.g-1和0.1ng.g-1.DBDPE,TBBPA-DBPE,BTBPE在沉积物和土壤样品中测定结果的相对标准偏差分别为16.29%,0.045%,0.051%.方法具有较低的方法检出限,较好的回收率和重复性,适用于一般环境样品中新型溴代阻燃剂的分析和检测.
英文摘要：
Three novel brominated flame retardants （BFRs） decabromodiphenyl ethane （DBDPE）, tetrabromobisphenol A bis （ 2,3-dibromopropyl ether） （ TBBPA-DBPE ） and 1,2-bis （ 2,4,6-tribromophenoxy ） ethane （BTBPE） in soil and sediment samples, were identified and quantified. The method was based on Soxhlet extraction, multilayer silica and alumina column for clean-up, and subsequent analysis by GC-MS using both electron ionization （EI） and electron capture negative ionization （ECNI） modes. The target compounds were under the limit of detection in the procedural blanks and their recoveries were in the range of 74. 8%-- 82.5%, 88.9%--100.7% and 86.7%--102.3% for DBDPE, TBBPA-DBPE, and BTBPE in the spike blanks, respectively. The average relative standard deviations （RSD） for the repeatability of analysis of soil and sediment samples were 16.29%, 0. 045% and 0. 051% for DBDPE, TBBPA-DBPE and BTBPE, respectively. Our results showed that the methods we adopted were certified for the analysis of the emerging novel BFRs in the environment.
同期刊论文项目
同项目期刊论文
Isomer-specific bioaccumulation and trophic transfer of dechlorane plus in the freshwater food web f
Polybrominated diphenyl ethers (PBDEs ), polychlorinated biphenyles (PCBs), hydroxylated and methoxy
Synthesis and characterization of novel SiO2 and TiO2 co-pillared montmorillonite composite for adso
Polychlorinated biphenyls and organochlorinated pesticides in various bird species collected from No
Brominated flame retardants , polychlorinated biphenyls and organochlorine pesticides in bird eggs f
Bioaccumulation of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in wi
Organochlorine pesticides in the surface water and sediments of the Pearl River Estuary, South China
Brominated Flame Retardants, Polychlorinated Biphenyls, and Organochlorine Pesticides in Giant Panda
Characterization and Photocatalytic Activity of Hydrophobic TiO2-montmorillonite photocatalysts: Deg
Sequential ASE Extraction of Polycyclic Aromatic Hydrocarbons with Different Solvents: Performance a
Oxidation of triclosan by ferrate: reaction kinetics, products identification and toxicity evaluatio
Fecal steroids in riverine runoff of the Pearl River Delta, South China: Levels, potential sources a
Carbon isotope analysis for source identification of atmospheric formaldehyde and acetaldehyde in Di
The factors controlling the partitioning of polybrominated diphenyl ethers and polychlorinated biphe
Polycyclic aromatic hydrocarbons in surface sediments of a highly urbanized river system with specia
Distribution and accumulation of endocrine-disrupting chemicals and pharmaceuticals in wastewater ir
Trends in the occurrence of human and veterinary antibiotics in the sediments of the Yellow River, H
Sorption of Polybrominatd Diphenyl Ethers (PBDEs) in Low-Density Polyethylene Film: Implications for
Advances in the study of current-use non-PBDE brominated flame retardants and dechlorane plus in the
Contaminant pattern and bioaccumulation of legacy and emerging organhalogen pollutants in the aquati
Fate of polybrominated diphenyl ethers in the environment of the Pearl River Estuary, South China En
A density functional study of the structural and electronic properties of silicon monoxide clusters.
Bioaccumulation potential of Dechlorane Plus in sediment-bearing fish from an e-waste recycling site
Selected Organochlorine Pesticides in the Atmosphere of Major Indian Cities: Levels, Regional versus
Passive sampling techniques for sensing freely dissolved hydrophobic organic chemicals in sediment p
Input pathways of organochlorine pesticides to typical freshwater cultured fish ponds of South China
Tissue distribution of dechlorane plus and its dechlorinated products in contaminated bottom fish: H
Simultaneous determination of benzotriazoles and ultraviolet filters in ground water, effluent and b
Photolysis of benzotriazole and formation of its polymerized photoproducts in aqueous solutions unde
Particle deposition fluxes of BDE-209, PAHs, DDTs and chlordane in the Pearl River Delta, South Chin
Air-soil exchange of dimethyl sulfide, carbon disulfide, and dimethyl disulfide in three subtropical
Occurrence of polybrominated biphenyl ethers in air and precipitation of the Pearl River Delta, Sout
Screening of multiple hormonal activities in surface water and sediment from the Pearl River system,
Photostability of the UV filter benzophenone-3 and its effect on photodegradation of benzotriazole i
Gas chromatography-mass spectrometry and high performance liquid chromatography-tandem mass spectrom
Persistent halogenated compounds in aquaculture environments of South China: Implications for global
Characterization and risk assessment of polychlorinated biphenyls in soils and vegetations near an e
Occurrence, bioaccumulation and potential sources of polybrominated diphenyl ethers in typical fresh
Characterization and risk assessment of PBDEs in soils and vegetations near an electronic waste recy
The influence of temperature and aerosol acidity on biogenic secondary organic aerosol tracers: Obse
Biomonitoring potentials of polycyclic aromatic hydrocarbons (PAHs) by higher plants from an oil exp
Polycyclic aromatic hydrocarbons in sediments and soils from oil exploration areas of the Niger Delt
Comparing polybrominated diphenyl ethers (PBDEs) in airborne particles in Guangzhou and Hong Kong: s
Dissipation of sulfamethoxazole, trimethoprim and tylosin in a soil under aerobic and anoxic conditi
Occurrence and risk assessment of acidic pharmaceuticals in the Yellow River, Hai River and Liao Riv
Dechlorane plus in house dust from E-waste recycling and urban areas in South China: Sources, degrad
Broadening the global reach of the United States Environmental Protection Agency (USEPA) is vital to
Bioaccumulation and historical deposition of polybrominated diphenyl ethers (PBDEs) in Deep Bay, Sou
UV-spectroscopy, electronic structure and ozonolytic reactivity of sesquiterpenes: a theoretical stu
Brominated flame retardants in house dust from e-waste and urban areas in South China and the implic
Dry and wet particle deposition of polybrominated diphenyl ethers (PBDEs) in Guangzhou and Hong Kong
Fate of linear alkylbenzenes and benzothiazoles of anthropogenic origin and their potential as envir
Occurrence, source diagnosis, and biological effect assessment of DDT and its metabolites in various
Bioaccumulation and trophic transfer of polybrominated diphenyl ethers (PBDEs) in biota from the Pea
Equilibrium and kinetic solid-phase microextraction (SPME) determination of the partition coefficien
Measurements of coeluting unlabeled and 13C-labeled polychlorinated biphenyl (PCB) congeners with pa
Rapid resolution liquid chromatography-tandem mass spectrometry method for the determination of endo
Inputs of antifouling paint-derived dichlorodiphenyltrichloroethanes (DDTs) to a typical mariculture
Brominated flame retardants in the atmosphere of e-waste and rural sites in Southern China: temporal
Atmospheric deposition of halogenated flame retardants at urban, e-waste, and rural locations in sou
Altered development and reproduction in western mosquitofish (Gambusia affinis) found in the Hanxi R
Occurrence and risks of triclosan and triclocarban in the Pearl River system, South China: From sour
Brominated flame retardants in children’s toys : concentration, composition, and children’s exposure
Contamination and screening level toxicity of sediments from remediated and unremediated wetlands ne
Biomagnification of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls (PCBs) in a
Residues of polybrominated diphenyl ethers in frogs (Rana limnocharis) from a contaminated site, Sou
Trace analysis of 28 steroids in surface water, wastewater and sludge samples by rapid resolution li
Spatial and seasonal distribution of selected antibiotics in surface waters of the Pearl Rivers, Chi
Atmospheric organochlorinated compounds at a remote site in Southwestern China: Implications for mon
Distribution of polycyclic musks in surface sediments from the Pearl River Delta and Macao coastal r
Distribution, source apportionment, and transport of PAHs in sediments from the Pearl River Delta an
Tracing sewage pollution in the Pearl River Delta and its adjacent coastal area of South China Sea u
Distribution and partition of polycyclic aromatic hydrocarbon in surface water of the Pearl River Es
Polybrominated diphenyl ethers (PBDEs) in free-range domestic fowl from an e-waste recycling site in
Polybrominated diphenyl ethers in road and farmland soils from an e-waste recycling region in Southe
Biomagnification of polybrominated diphenyl ethers (PBDEs) and polychlorinated biphenyls in a highly
期刊信息
位置：