利用简单的水热法以及后续热处理,将钴酸镍纳米花成功生长在活性炭纤维支架上.场发射扫描电镜(FESEM)及透射电镜(TEM)结果表明,纳米花是由纳米针自组装而成,而纳米针呈多孔结构.这种三维复合多级结构非常有利于电解质离子的渗透和电子的传输.将该多孔钴酸镍纳米花,活性炭纤维布作为工作电极,表现出优良的电容性能.在1A·g^-1时,比电容高达1626F·g^-1;在10A·g^-1时,电容保持率为65%,具有超高的电容值和优异的倍率特性.
In the present work, NiCo20, nanowires grown directly on carbon fibers self-organize into a nanoflower morphology. The materials are prepared by hydrothermal treatment and subsequent low-temperature annealing. Field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) results reveal a hierarchical three-dimensional mesoporous structure, which facilitates ion transport and electronic conduction for fast redox reactions. As a result, the electrode achieves a respectable specific capacitance of 1626 F· g^-1 at 1 A· g^-1 and high rate capability (65% retention at 10 A· g^-1), so it shows promise for application in supercapacitors.