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古代玻璃样品表面因素对便携式X射线荧光定量分析的影响
  • ISSN号:1000-0593
  • 期刊名称:光谱学与光谱分析
  • 时间:2011.7.7
  • 页码:1954-1959
  • 分类:S831.5[农业科学—畜牧学;农业科学—畜牧兽医] TS933.21[轻工技术与工程]
  • 作者机构:[1]Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China, [2]Shanghai Mass Spectrometry Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China, [3]Fudan University, Shanghai 200433, China
  • 相关基金:Project supportect by the National Natural Science Foundation of~China (No. 51072208), the Startup Funding of Chinese Academy of Sciences (No. O87YQ1110G), the Plan of the Creative Funding of Shanghai Institute of Ceramics, Chinese Academy of Sciences (No. O97ZC1110G), and the Plan of the Creative Funding of the Ministry of Science and Technology of the People's Republic of China (No. 2009IM031100).
  • 相关项目:长江中下游流域出土新石器时代古玉的科技研究
中文摘要:

软玉矿物质的元素特征被发光分泌物团 spectrometry (GDMS ) 通过表面坚持方法决定。解决非传导性的软玉样品的传导性问题,高纯净铟大头针(>99.9999%) 是被使用分泌物主人。在准备过程期间,软玉样品的一小片被磨成粉末(大约 200 个网孔) ,然后样品粉末在铟大头针的表面上是涂的形成一件杆样品。软玉矿物质的典型元素被 GDMS 分析,并且相对标准差证明这个方法的稳定性和重制度好。同时,从二不同沉积物的四件软玉样品被这个方法进一步学习。主要元素和踪迹元素的 GDMS 结果表明从一样的沉积物的软玉矿物质的典型元素是类似的,并且那些从不同沉积物展出了重要差别。另外,外部横梁的质子的结果导致了 X 光检查排放(PIXE ) 与 GDMS 决心的结果一致。现在的途径被证明了简单,有效软玉的半量的分析取样执行快速的屏蔽和多元素。

英文摘要:

Element characteristics of nephrite minerals were determined by glow discharge mass spectrometry (GD-MS) through surface adherence method. To solve the conductivity problem of non-conductive nephrite samples, high purity indium pin (〉99.9999%) was used as discharge host. During the preparation procedure, a small piece of nephrite sample was ground into powder (about 200 meshes), and then the sample powder was coated on the surface of indium pin to form a rod sample. Typical elements of nephrite minerals were analyzed by GD-MS, and the relative standard deviations showed that the stability and reproducibility of this method were good. Meanwhile, four nephrite samples from two different deposits were further studied by this method. The GD-MS results of major elements and trace elements revealed that typical elements of the nephrite minerals from same deposit were similar, and those from different deposits exhibited significant difference. In addition, results of external-beam proton induced X-ray emission (PIXE) were consistent with the result of GD-MS determination. The present approach had been proven to be simple, efficient to perform the rapid screening and multi-element semi-quantitative analysis of nephrite samples.

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期刊信息
  • 《光谱学与光谱分析》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国光学学会
  • 主编:高松
  • 地址:北京海淀区魏公村学院南路76号
  • 邮编:100081
  • 邮箱:chngpxygpfx@vip.sina.com
  • 电话:010-62181070
  • 国际标准刊号:ISSN:1000-0593
  • 国内统一刊号:ISSN:11-2200/O4
  • 邮发代号:82-68
  • 获奖情况:
  • 1992年北京出版局编辑质量奖,1996年中国科协优秀科技期刊奖,1997-2000获中国科协择优支持基础性高科技学术期刊奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国生物医学检索系统,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:40642