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锆离子改善十烷基磷酸组装膜结构及性能研究
  • 期刊名称:电化学,14(2),175-179,2008
  • 时间:0
  • 分类:O646[理学—物理化学;理学—化学]
  • 作者机构:[1]上海师范大学生命与环境科学学院,上海200234
  • 相关基金:国家自然科学基金(20503016),上海市科委启明星计划(07QA14044)资助
  • 相关项目:功能化室温离子液体中金属卟啉与气体分子的相互作用规律
中文摘要:

利用烷基磷酸、金属锆离子和不锈钢电极表面的相互作用,通过表面自组装,在304不锈钢电极表面分别修饰了单层和双层烷基磷酸自组装膜,采用接触角和极化曲线对修饰电极进行测量.实验表明,双层烷基磷酸修饰膜具有更佳的耐腐蚀性能.

英文摘要:

According to the complex interaction between dodecyl phosphonate and stainless steel surface as well as the zirconium ion, the self-assembled monolayer and double-layer dodecyl phosphonate modified 304 type stainless steel electrode were prepared. The electrodes were characteristiced by static contact angles and electrochemical polarization methods. The results suggested that the double-layer modified stainless steel electrode had better corrosion inhibition effect than the monolayer modified electrode.

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