一系列聚乙二醇双咪唑型离子液体被合成和表征,并应用于Rh Cl3催化烯烃硅氢加成反应中。考察了Rh Cl3用量、离子液体用量、反应温度和反应时间对催化结果的影响。在低温、无溶剂条件下,该催化剂体系表现出较高的转化率和良好的选择性。
A series of polyethylene glycol( PEG) double imidazole ionic liquids have been synthesized,characterized and applied in catalyzed hydrosilylation of olefin by Rh Cl3. The effects of the amount of Rh Cl3 and ionic liquid,reaction temperature and reaction time on the reaction were investigated.Under solvent-free and low temperature,the catalysis system showed good catalytic performance.