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苯乙烯基氨甲基香豆素衍生物的合成以及对Fe3＋的识别
  • ISSN号：0253-2395
  • 期刊名称：《山西大学学报：自然科学版》
  • 时间：0
  • 分类：O626[理学—有机化学;理学—化学]
  • 作者机构：[1]山西大学化学化工学院,山西太原030006
  • 相关基金：国家自然科学基金（21175087）;山西省青年基金（2012011007-2）;山西省大学生创新项目（120164063）
作者： 武宏娟[1], 庞宗文[1], 张彩红[1], 范萌[1], 双少敏[1]
关键词： 香豆素衍生物, TSAC, FE3+, 荧光光谱, coumarin derivatives , TSAC, Fe3＋ , fluorescence spectra
中文摘要：

以4，6-二甲基香豆素为原料，通过Wittig反应引入苯环延长其电子共轭体系，再经N-溴代丁二酰亚胺（NBS）溴代，然后与二乙醇胺反应、乙酰氯酯化得到一种新型的苯乙烯基氨甲基香豆素衍生物4-[trans’4-（甲酸甲酯）-苯乙烯基]-6-[二（2-乙酰氧乙基）氨甲基]-香豆素（TSAC），并对其结构进行了核磁表征．通过紫外和荧光分光光度法研究了它与金属离子的相互作用，结果表明TSAC对Fe件有选择性识别的性能．

英文摘要：

4-（ trans-4-methylformate-styryl）-6-[bis-（2-acetoxyethyl） aminomethyl]-coumarin （TSAC） was synthesized by a series of reaction including wittig and substitution etc. from 4,6-dimethy[ coumarin and characterized by UV-vis absorption spectra. The structure of TSAC was characterized by 1H NMR. The in- teraction between TSAC and metal ions was studied via fluorescence spectra. The results showed TSAC could recognize Fe3＋ selectively.

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期刊信息
  • 《山西大学学报：自然科学版》
  • 北大核心期刊（2011版）
  • 主管单位:山西省教育厅
  • 主办单位:山西大学
  • 主编：杨斌盛
  • 地址：太原市坞城路92号
  • 邮编：030006
  • 邮箱：xbbjb@sxu.edu.cn
  • 电话：0351-7010455
  • 国际标准刊号：ISSN：0253-2395
  • 国内统一刊号：ISSN：14-1105/N
  • 邮发代号:22-42
  • 获奖情况:
  • 边疆七年获山西省一级期刊荣誉（1993-1999）
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,英国动物学记录,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:5651