以乙炔选择性加氢为模型反应,探讨了载体TiO2的制备条件对催化剂Pd/TiO2催化性能的影响:实验结果表明,在pH=8.0,中速加钛源,陈化24h,500℃焙烧3h的最佳制备条件下,Pd/TiO2的催化性能最佳。TiO2的结构经XRD和BET表征。
TiO2 supports were prepared and used in supported palladium catalysts for selective hydrogenation of acetylene. The preparation conditions of pH = 8.0, 24 h aging and calcining at 500 ℃ for 3 h gave the TiO2-supported Pd catalyst with better performance in hydrogenation of acetylene.