位置:成果数据库 > 期刊 > 期刊详情页
地下河流域土壤中有机氯农药分布及来源分析
  • ISSN号:1000-6923
  • 期刊名称:《中国环境科学》
  • 时间:0
  • 分类:X53[环境科学与工程—环境工程]
  • 作者机构:[1]西南大学三峡库区生态环境教育部重点实验室,重庆400715
  • 相关基金:重庆市科委院士专项(CSTS,2010BC7004);家自然科学基金资助项目(41072192,41040026);中央高校基本科研业务费专项资金项(XDJK20108006)
中文摘要:

为研究有机氯农药在重庆青木关地下河流域土壤中的分布特征及来源,采用GC-uECD对17个代表性表层土壤样品进行分析.结果显示,研究区土壤中OCPs的含量范围是7.29-222.42ng/g,平均值为46.15ng/g.HCHs、DDTs在所有样品中均有检出,HCHs的含量范围是0.55-26.54ng/g,DDTs的含量范围是4.31-213.50nedg.HCB的检出率达到88%,其含量范围是n.d.-1.78ng/g.研究区土壤中HCHs可能来源于工业HCHs残留和林丹的混合源,且由于环境影响,土壤中HCH的同系物之间发生了明显变化.DDTs主要来源于工业DDTs的非法使用,而非三氯杀螨醇类型的DDTs,并且仍有新的DDTs输入.与国内其他地区同类研究相比,本研究区土壤中HCHs、DDTs的残留水平较低;与国外相关研究相比。研究区内土壤中HCHs和DDTs的含量均高于德国、埃及、罗马尼亚土壤中HCHs和DDTs的含量。

英文摘要:

In order to study the distribution tendency and main possible sources of organochlorine pesticides (OCPs) in Qingmugnan underground river catchment in Chongqing, the concentrations of OCPs residues in 17 topsoil samples were measured by gas chromatography equipped with miro-63Ni electron capture detector. The total OCPs concentrations in soils of Qingmuguan ranged from 7.29 to 222.42ng/g with an average value of 46.15ng/g. HCHs and DDTs existed in all samples. The concentrations of HCHs ranged from 0.55 to 26.54rig/g, wihle the concentration of DDTs ranged from 4.31 to 213.50ng/g. The detectable rate of HCB was 88%, and the concentrations of HCB ranged from n.d. to 1.78ng/g. HCHs in study area came from industrial HCHs and lindane, meanwhile, the compositions of HCH isomers has changed significantly under the impact of environment. There were still fresh inputs of DDTs to soils in Qingmugnan underground river catchment, which substantially originated from illegal use of industrial DDTs rather than the dicofol type of DDT. HCB was a kind of persistent organic pollutants which widely existed in soils of Qingmuguan, and mainly being produced by the regional air deposition in recent years. Compared to the similar researches in other areas in China, HCHs and DDTs residues in the soil of Qingmuguan presented low levels. Furthermore, They were higher than those of Germany, Egypt, Romania when compared with parallel researches worldwide.

同期刊论文项目
同项目期刊论文
期刊信息
  • 《中国环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国环境科学学会
  • 主编:王文兴
  • 地址:北京市海淀区红联南村54号
  • 邮编:100082
  • 邮箱:zghjkx1981@126.com
  • 电话:010-62215145
  • 国际标准刊号:ISSN:1000-6923
  • 国内统一刊号:ISSN:11-2201/X
  • 邮发代号:2-572
  • 获奖情况:
  • 国家期刊提名奖,国家“双效”期刊,第三届中国科协优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,波兰哥白尼索引,荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,英国科学文摘数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:47702