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青藏高原淡水湖泊水化学组成特征及其演化
  • ISSN号:0250-3301
  • 期刊名称:环境科学
  • 时间:2013.3.3
  • 页码:874-881
  • 分类:X524[环境科学与工程—环境工程]
  • 作者机构:[1]西南大学地理科学学院,三峡库区生态环境教育部重点实验室,重庆400715, [2]成都市环境保护科学研究院,成都610072
  • 相关基金:国家自然科学基金项目(41072192,41103068); 中央高校基本科研业务费专项(XDJK2010B006); 重庆市科委院士专项(CSTS,2010BC7004); 高等学校博士学科点专项科研基金项目(20100182120029); 岩溶动力学重点实验室开放课题项目(KDL2011-04)
  • 相关项目:岩溶碳汇重要科学问题研究
中文摘要:

青藏高原淡水湖具有高生态价值和高脆弱性并存的特点.以海拔5 080 m±10 m的打加芒错湖水为研究对象,测试及分析了湖水化学组分,探讨了其主要离子来源、控制因子和湖泊水化学演化趋势.结果表明,湖水阳离子以Ca2+和Na+为主,阴离子以HCO3-为主,为HCO3-Ca型水;TDS为71.2~199.8 mg·L-1,矿化度低;受地表径流的稀释作用和富铝贫钙的地质背景约束湖区东南部水体的EC、Ca2+和HCO3-浓度均较低.湖水的Na+/(Na++Ca2+)为0.08~0.75,Cl-/(Cl-+HCO3-)为0.11~0.35,Ca/Na值为0.58,Mg/Ca值为0.12,HCO3/Na值为1.46,据Gibbs模型和元素化学计量分析表明,其化学组成主要受硅酸盐岩风化控制.湖区流域参与风化的矿物岩石包括斜长石(钙长石、钠长石)、钾长石、云母、石膏、盐岩等,但以斜长石风化为主,湖水的K/Na值平均为0.059,表明流域钾长石风化程度较低.湖水中方解石、白云石、石英、石膏等矿物饱和指数(SI)大于0,石盐的SI则小于0,揭示了青藏高原上淡水湖泊演变成咸水湖的变化趋势.

英文摘要:

Freshwater lake of the Tibetan plateau has great ecological value and extreme vulnerability. The water samples have been collected in Daggyaima Co at an altitude of 5 080 m ± 10 m. This study has investigated the sources, the major controlling factors of the major ions, and hydroehemieal evolution trend according to the hydrochemical composition of water samples. The results showed that the major cations and anion of lake water were Ca2+ , Na+ and HCO3- , respectively, and the hydrocbemical type was HCO3-Ca, The total dissolved solid (TDS) was in the range of 71.2-199.8 mg.L-l. The concentrations of EC, Ca2+ and HCO3- in water samples from Southeast areas were relatively low resulted from the rich aluminum and poor calcium of geological background and the dilution effect of surface runoff. TheNa +/(Na + +Ca2 +) of water samples was0.08-0.75, Cl-/(C1- +HCO3-) was0.11-0.35, Ca/Nawas 0.58, Mg/Ca was 0.12, and HCO3/Na was 1.46, which suggested that the hydrochemical composition of the lake water was mainly controlled by silicate rock weathering based on Gibbs model and analysis of elemental stoichiometry. The minerals participated in weathering processes included plagioclase (anorthite, albite) , potassium feldspar, biotite, calcite, dolomite, gypsum, rock salt, etc. The average value of K/Na was 0. 059, indicating the weathering level of potassium feldspar was relatively low. The saturation index (SI) of calcite, dolomite, gypsum, quartz and hematite contained in the lake was higher than zero, while the SI of rock salt was lower than 0, revealing the trend that the freshwater lake is turning into salt water lake in Tibetan Plateau.

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期刊信息
  • 《环境科学》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:赵进才
  • 地址:北京市2871信箱(海淀区双清路18号)
  • 邮编:100085
  • 邮箱:hjkx@rcees.ac.cn
  • 电话:010-62941102 62849343
  • 国际标准刊号:ISSN:0250-3301
  • 国内统一刊号:ISSN:11-1895/X
  • 邮发代号:2-821
  • 获奖情况:
  • 在全国第一届和第二届优秀科技期刊评比中分别荣获...,二次荣获中国科学院优秀期刊评比一等奖,荣获中国期刊方阵双奖期刊荣誉
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国生物医学检索系统,美国剑桥科学文摘,美国生物科学数据库,英国动物学记录,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:69962