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中文摘要：
采用水热法合成了一种新的三维配位聚合物[Zn6（bta）4（2,2′-bipy）3]（H3bta=1,3,5-苯三乙酸;2,2′-bipy=2,2′-二联吡啶）,并通过X射线单晶结构分析、红外光谱、元素分析和热重分析对该配合物进行了表征.结构分析数据表明,该配合物属单斜晶系,Cc空间群,晶胞参数a=1.7714（4）nm,b=2.4391（5）nm,c=1.7120（3）nm,β=104·39（3）°,Z=4,V=7·165（2）nm^3,Dc=1·722g/cm^3,μ=2·065mm^-1,F（000）=3768,R1=0·0645,wR2=0·1424.荧光光谱结果表明,配合物具有良好的荧光性质.
英文摘要：
A novel coordination polymer [ Zn6 （bta） 4 （2,2＇-bipy） 3 ], with three-dimensional structure, was obtained via assembly of flexible tripodal ligand 1,3,5-benzenetriacetic acid（ H3bta） with 2, 2＇-bipy, Zn（ NO3 ）3· 6H2O under the hydrothermal condition. The X-ray single crystal diffraction analysis reveals that the complex is monoclinic with space group Cc, a = 1. 7714（4） nm, b =2. 4391 （5） nm, c = 1. 7120（3） nm, fl = 104. 39（3）°, Z =4, V =7. 165（2） nm^3, Dc = 1. 722 g/cm^3,μ = 2. 065 mm^-1, F（000） = 3768, R1 = 0. 0645, wR2 = 0. 1424 for 8019 observed reflections with goodness-of-fit 1. 050. The photoluminescence property of the complex in the solid state was studied at room temperature and strong blue emission was observed.
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