对羧甲基纤维素(CMC)进行改性,并将其用于吸附废水中的铀.研究结果表明:在温度为70℃-80℃、单体质量浓度为30%-35%、羧甲基纤维素:丙烯酸(质量比)为10:2.5、反应时间为3.5-4h条件下,CMC改性效果最好;在改性CMC质量浓度为O.10g/L,温度为25℃,pH值为5.0,反应时间60min的条件下,对废水中铀去除率达到了97.1%;改性CMC对溶液中U(VI)的吸附过程符合Freundlich方程,其吸附动力学数据符合准一级方程(R^2=0.9618),表明改性CMC的吸附主要是表面吸附;热力学研究表明,改性CMC对铀的吸附吉布斯自由能(△G^0)〈0,而焓变(△H^0)〉0,吸附过程是自发的吸热反应、以物理吸附为主的过程.
The acrylic acid(AA)-modified carboxymethyl cellulose(CMC) resin was prepared and was explored to adsorb uranium(VI) ions fi'om aqueous solution in a batch system. The experimental results showed that on the condition of reaction tempomture 70-80℃, CIVIC 30% -35% (w/w), CMC to AA (w/w) of 10:2.5 and reaction time 3.5-4h, the modification effect was the best. High removal efficient of U(VI) was obtained 97.1% at temperature of 25℃, pH value of 5.0, dosage of modified CMC resin 0.1 g/L and contact time of 60 min. It was found that the adsorption process was best described by Freundiich model and pseudo-first-order kinetic model (R^2=0.9618), indicating that the adsorption was mainly on the surface of the resin. Thermodynamics parameters of negative value of △G^0 and positive value of △H^0 revealed the spontaneity and endothermic nature of the adsorption. The adsorption was primarily due to physical adsorption.