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Synthesis of an Anionic Receptor Based on Phenylhydrazone Group and Its Recognition Property for Acetate
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 时间：0
  • 分类：O625[理学—有机化学;理学—化学]
  • 作者机构：[1]Department of Chemistry, Nankai University, Tianjin 300071, China, [2]Key Laboratory of Functional Polymer Materials of Ministry of Education, Nankai University, Tianjin 300071, China
  • 相关基金：Project supported by the National Natural Science Foundation of China （No. 20371028, 20671052） and the Natural Science Foundation of Tianjin of China （No. 023605811）.
作者： 王月红[1], 林海[2], 林华宽[1]
关键词： 阴离子受体, 苯腙, 醋酸盐, 比色识别, 氢键, receptor, phenylhydrazone, anion, colorimetric recognition, hydrogen bond
中文摘要：

比色的阴离子受体被 phenylhydrazone 一半作为有约束力的地点是需要的一个简单方法综合。经由结合氢的相互作用的阴离子识别能被阴离子 complexation 容易监视在紫外力的吸收系列的导致的变化。而且，在 phenylhydrazone NH 和醋酸盐或氟化物阴离子之间的氢契约形成根据 1H NMR 实验被描述。

英文摘要：

A colorimetric anion receptor was synthesized by a simple method where the phenylhydrazone moiety was need as binding sites. The anion recognition via hydrogen-bonding interactions can be easily monitored by anion complexation induced changes in UV-vis absorption spectra. Moreover, the hydrogen bond formation between the phenylhydrazone N-H and acetate or fluoride anion was described on the basis of ^1H NMR experiments.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175