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定向凝固Ti—43Al—3Si合金的组织演化规律Ⅰ.初始过渡区组织演化规律
  • ISSN号:0412-1961
  • 期刊名称:《金属学报》
  • 时间:0
  • 分类:TG249.9[金属学及工艺—铸造]
  • 作者机构:[1]哈尔滨工业大学材料科学与工程学院,哈尔滨150001, [2]华中科技大学模具技术国家重点实验室,武汉430074
  • 相关基金:国家自然科学基金项目51071062和50801019; 华中科技大学模具技术国家重点实验室开放基金项目2011-P03; 国家重点基础发展计划项目2011CB610406资助
中文摘要:

采用液淬方法对Al-11.80Cu-24.22Mg(质量分数,%)三元包共晶合金在不同温度下淬火,而后,对其相组成和凝固组织进行了研究,对凝固组织的演化规律以及凝固机制进行了分析.实验结果表明,该合金凝固过程中确实发生了三元包共晶反应,初生相为S相(Al_2CuMg),包共晶组织为α-Al相和T相(Al_6CuMg_4)组成,最终凝固组织由残余初生S相、包共晶组织(α-Al+T)、两相共晶(α-Al+T)及三相共晶(α-Al+T+β)组成;虽然包共晶组织中和两相共晶中含有相同的相,即α-(Al)相和T相,但二者的组织形态不同,包共晶组织呈"条带状",而两相共晶呈规则的"蛛网状"和"球状".此外,三元包共晶反应时,包共晶组织依附于初生S相的周围生长,随着冷却速率的增加,三元包共晶反应变慢甚至被抑制,致使初生S相剩余而滞留在基体中.

英文摘要:

In the field of condensed matter physics and materials science,it is of great importance to investigate the microstructures,properties and solidification regularities of liquid metals.In the last few decades,the theories of solidification of binary alloys,such as dendritic growth and eutectic growths have been built.Great progress has also been made on the study of monetectic and peritectic alloys. But a solidification theory on ternary quasiperitectic alloys has not been established up to now.The study of the solidification process of quasiperitectic alloys will provide a basic work for solidification theories of ternary alloys. The master alloy of Al-11.8Cu-24.22Mg was prepared from pure Al(99.99%),pure Mg(99.99%) and Al-54.2Cu in a resistance furnace under CO_2 and SF_6(volume proportion is 40:1) atmosphere. The melted alloy(840—850℃) was pouring into different quenching graphite crucibles at the same time,and the cooling curves were recorded by a sixteen channels temperature recorder.The graphite crucible was quenched into cold-water immediately for rapid cooling at the preplanned quenching temperature.After the experiment,the microstructures of the sample were analyzed by SEM,with EDS analysis. The experiment result indicates that the primary phase is identified as S(Al_2CuMg) and the quasiperitectic phases areα-Al and T(Al_6CuMg_4).The solidification microstructure is composed of remnant primary phase,quasiperitectic phases,binary eutectic and ternary eutectic.Although the quasiperitectic phases and binary eutectic are composed of the same phases(α-Al+T(Al_6CuMg_4)), their structures are different.The former structure presents strip form and the later present dendritic form.The ternary eutectic reaction is suppressed and the remnant primary S phase is reserved in the matrix with non-equilibrating crystallization.

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期刊信息
  • 《金属学报》
  • 中国科技核心期刊
  • 主管单位:中国科学协术协会
  • 主办单位:中国金属学会
  • 主编:柯俊
  • 地址:沈阳文化路72号
  • 邮编:110016
  • 邮箱:shxiao@imr.ac.cn
  • 电话:024-23971286
  • 国际标准刊号:ISSN:0412-1961
  • 国内统一刊号:ISSN:21-1139/TG
  • 邮发代号:2-361
  • 获奖情况:
  • 第一、二届全国优秀科技期刊评比一等奖,第一、二、三届国家期刊奖,国家期刊方阵"双高"期刊,第一、二、三届中国科学院科技期刊评比一等奖,中国科学院优秀期刊特别奖,第一、二、三、五届中国科协优秀科技期刊评比一等奖,中国科协精品期刊工程A类、B类,第一、二、三、四、五届中国百种杰出学术期刊,首届出版政府奖
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  • 被引量:26785