中文摘要：

以4-氯苯乙酸为起始原料,耦合酯化和还原反应合成了4-氯苯乙醇（1）,其结构经1H NMR和MS表征。较适宜的反应条件为：4-氯苯乙酸30 mmol,无水乙醇120 mmol,n（4-氯苯乙酸）∶n（SOCl2）∶n（NaBH4）=1.0∶0.5∶1.6,于室温反应3 h完成酯化反应,产物不经分离直接于75℃反应5 h完成还原反应,1收率高于95%,含量大于99%。

英文摘要：

2-（4-Chlorophenyl）ethanol（1） was synthesized by esterification and reduction from 2-（4-chlorophenyl） acetic acid（3）. The structure was characterized by ^1H NMR and MS. The appropriate reaction conditions were as follows： 3 was 30 retool, ethanot was 120 retool, n （ 3 ） ： n （ SOCl2 ） ： n （ NaBH4） was 1.0 ： 0.5 ： 1.6. The yield of 1 was over 95% by esterification at room temperature for 3 h and reduction at 75℃ for 5 h.